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Facile synthesis of a flexible tethered porphyrin dimer that preferentially complexes fullerene C70.


ABSTRACT: A simple, high yield, two-step synthesis yields a porphyrin dimer linked by a flexible dithiol tether that preferentially binds fullerene C(70) over C(60) in toluene solution. The complex forms stable aggregates when cast on glass.

SUBMITTER: Jurow M 

PROVIDER: S-EPMC6011656 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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Facile synthesis of a flexible tethered porphyrin dimer that preferentially complexes fullerene C70.

Jurow Matthew M   Farley Christopher C   Pabon Cesar C   Hageman Brian B   Dolor Aaron A   Drain Charles Michael CM  

Chemical communications (Cambridge, England) 20120410 39


A simple, high yield, two-step synthesis yields a porphyrin dimer linked by a flexible dithiol tether that preferentially binds fullerene C(70) over C(60) in toluene solution. The complex forms stable aggregates when cast on glass. ...[more]

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