Ontology highlight
ABSTRACT:
SUBMITTER: Rosenzweig MW
PROVIDER: S-EPMC6024247 | biostudies-literature | 2016 Sep
REPOSITORIES: biostudies-literature
Chemical science 20160510 9
Herein, we report the synthesis and characterization of a series of terminal uranium(iv) hydrosulfido and sulfido complexes, supported by the hexadentate, tacn-based ligand framework (<sup>Ad,Me</sup>ArO)<sub>3</sub>tacn<sup>3-</sup> (= trianion of 1,4,7-tris(3-(1-adamantyl)-5-methyl-2-hydroxybenzyl)-1,4,7-triazacyclononane). The hydrosulfido complex [((<sup>Ad,Me</sup>ArO)<sub>3</sub>tacn)U-SH] (<b>2</b>) is obtained from the reaction of H<sub>2</sub>S with the uranium(iii) starting material [( ...[more]