On the Natural History of Flavin-Based Electron Bifurcation.
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ABSTRACT:
SUBMITTER: Baymann F
PROVIDER: S-EPMC6037941 | biostudies-literature | 2018
REPOSITORIES: biostudies-literature
Publications
On the Natural History of Flavin-Based Electron Bifurcation.
Baymann Frauke F Schoepp-Cothenet Barbara B Duval Simon S Guiral Marianne M Brugna Myriam M Baffert Carole C Russell Michael J MJ Nitschke Wolfgang W
Frontiers in microbiology 20180703
Electron bifurcation is here described as a special case of the continuum of electron transfer reactions accessible to two-electron redox compounds with redox cooperativity. We argue that electron bifurcation is foremost an electrochemical phenomenon based on (a) strongly inverted redox potentials of the individual redox transitions, (b) a high endergonicity of the first redox transition, and (c) an escapement-type mechanism rendering completion of the first electron transfer contingent on occur ...[more]
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