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Crystal structure of homodinuclear platinum complex containing a metal-metal bond bridged by hydride and phosphide ligands.

ABSTRACT: In the title compound, ?-di-phenyl-phosphido-?-hydrido-bis-[bromido-(tri-phenyl-phosphane-?P)platinum(II)] diethyl ether monosolvate, [Pt₂Br₂(C₁₂H₁₀P)H(C₁₈H₁₅P)₂]·C₄H₁₀O or [Pt₂(?-H)(?-PPh₂)Br₂(PPh₃)₂]·(C₂H₅)₂O, the Pt^II atoms are coordinated in a distorted square-planar arrangement, with one hydrido and one phosphido ligand bridging in a trans position. In the lattice, C-H?·O and C-H?? interactions are present. This complex has a total number of 32 electrons, 16 electrons for each Pt^II atom. One of the Br atoms is disordered over two positions in a 0.92:0.08 ratio.

SUBMITTER: Ouis S

PROVIDER: S-EPMC6038636 | biostudies-literature | 2018 Jul

REPOSITORIES: biostudies-literature

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Crystal structure of homodinuclear platinum complex containing a metal-metal bond bridged by hydride and phosphide ligands.

Ouis Sakina S Rouag Djamil Azzedine DA Bendjeddou Lamia L Bailly Corinne C

Acta crystallographica. Section E, Crystallographic communications 20180619 Pt 7

In the title compound, μ-di-phenyl-phosphido-μ-hydrido-bis-[bromido-(tri-phenyl-phosphane-κP)platinum(II)] diethyl ether monosolvate, [Pt2Br2(C12H10P)H(C18H15P)2]·C4H10O or [Pt2(μ-H)(μ-PPh2)Br2(PPh3)2]·(C2H5)2O, the PtII atoms are coordinated in a distorted square-planar arrangement, with one h ...[more]

PMID: 30002898

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