Miscibility and Performance Evaluation of Biocomposites Made from Polypropylene/Poly(lactic acid)/Poly(hydroxybutyrate-co-hydroxyvalerate) with a Sustainable Biocarbon Filler.

ABSTRACT: The incorporation of poly(lactic acid) (PLA) and poly(hydroxybutyrate-co-hydroxyvalerate) (PHBV) as a partial biobased polymer substitute for polypropylene (PP) was investigated. The ternary blends were prepared through melt compounding extrusion followed by injection molding techniques with a constant biopolymer ratio of 30 wt %. Further addition of pyrolyzed miscanthus-based carbon was carried out to establish a contrast between talc-filled PP. When the morphology of the biopolymer minor phase was analyzed theoretically using contact angle for interfacial tension and spreading coefficient values along with solubility parameter calculations and via scanning electron microscopy imaging, the core-shell architecture was found with the PHBV encasing the PLA phase. Mechanical testing of the materials showed that only the tensile properties were reduced for all samples, whereas the impact strength was increased above the neat PP. With inclusion of the biobased carbon filler into the blend system, the thermomechanical properties were elevated above that of the PP matrix. The final properties of the multiphase polymeric composites are found to be related to the morphology obtained and inherent properties of the individual constituents.

SUBMITTER: Snowdon MR 

PROVIDER: S-EPMC6044961 | biostudies-literature | 2017 Oct

REPOSITORIES: biostudies-literature