Ontology highlight
ABSTRACT:
SUBMITTER: Li J
PROVIDER: S-EPMC6050601 | biostudies-literature | 2018 Jul
REPOSITORIES: biostudies-literature
Chemical science 20180601 26
Direct introduction of a difluoromethylthio group (-SCF<sub>2</sub>H) to arenes represents an efficient route to access a valuable catalogue of organofluorines; however, to realize this transformation under metal-free and mild conditions still remains challenging and rarely reported. Herein, a metal-catalyst-free and redox-neutral innate difluoromethylthiolation method with a shelf-stable and readily available reagent, PhSO<sub>2</sub>SCF<sub>2</sub>H, under visible light irradiation is describe ...[more]