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Modular O2 electroreduction activity in triphenylene-based metal-organic frameworks.

ABSTRACT: Triphenylene ligands hexasubstituted with amino or phenol groups afford two phases of electrically conductive layered two-dimensional metal-organic frameworks upon reaction with various metals. Regardless of the identity of the metal or chelating atom, ?-stacking within the MOF layers is essential to achieve high electrical conductivity, redox activity, and catalytic activity.

SUBMITTER: Miner EM 

PROVIDER: S-EPMC6063138 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature

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Modular O<sub>2</sub> electroreduction activity in triphenylene-based metal-organic frameworks.

Miner Elise M EM   Wang Lu L   Dincă Mircea M  

Chemical science 20180627 29

Triphenylene ligands hexasubstituted with amino or phenol groups afford two phases of electrically conductive layered two-dimensional metal-organic frameworks upon reaction with various metals. Regardless of the identity of the metal or chelating atom, π-stacking within the MOF layers is essential to achieve high electrical conductivity, redox activity, and catalytic activity. ...[more]

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