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Direct-Continuous Preparation of Nanostructured Titania-Silica Using Surfactant-Free Non-Scaffold Rice Starch Template.

ABSTRACT: The conventional synthesis route of nanostructured titania-silica (Ti-SiNS) based on sol-gel requires the use of a surfactant-type template that suffers from hazardous risks, environmental concerns, and a tedious stepwise process. Alternatively, biomaterials have been introduced as an indirect template, but still required for pre-suspended scaffold structures, which hinder their practical application. Herein, we report an easy and industrially viable direct-continuous strategy for the preparation of Ti-SiNS from nanostructured-silica (SiNS) using a hydrolyzed rice starch template. This strategy fits into the conventional industrial process flow, as it allows starch to be used directly in time-effective and less complicated steps, with the potential to upscale. The formation of Ti-SiNS is mainly attributed to Ti attachment in the SiNS frameworks after the polycondensation of the sol-gel composition under acidic-media. The SiNS had pseudo-spherical morphology (nanoparticles with the size of 13 to 22 nm), short order crystal structure (amorphous) and high surface area (538.74 m²·g⁻¹). The functionalized SiNS into Ti-SiNS delivered considerable catalytic activity for epoxidation of 1-naphtol into 1,4-naphthoquinone. The described direct-continuous preparation shows great promise for a cheap, green, and efficient synthesis of Ti-SiNS for advanced applications.

SUBMITTER: Matmin J

PROVIDER: S-EPMC6071009 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Hierarchically Porous Silica Prepared with Anionic Polyelectrolyte-Nonionic Surfactant Mesomorphous Complex as Dynamic Template.

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| S-EPMC8637971 | biostudies-literature

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| S-EPMC5953918 | biostudies-literature

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