Ontology highlight
ABSTRACT:
SUBMITTER: Hu H
PROVIDER: S-EPMC6100402 | biostudies-literature | 2018 Jul
REPOSITORIES: biostudies-literature
Molecules (Basel, Switzerland) 20180718 7
Beckmann rearrangement of ketoxime catalyzed by acidic ionic liquid-<i>N</i>-methyl-imidazolium hydrosulfate was studied. Rearrangement of benzophenone oxime gave the desirable product with 45% yield at 90 °C. When co-catalyst P₂O₅ was added, the yield could be improved to 91%. The catalyst could be reused three cycles with the same efficiency. Finally, reactions of other ketoximes were also investigated. ...[more]