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Influence of the Preparation Method and Photo-Oxidation Treatment on the Thermal and Gas Transport Properties of Dense Films Based on a Poly(ether-block-amide) Copolymer.

ABSTRACT: Dense films based on the hydrophobic Pebax^®2533 were prepared by using solution casting in different solvents as well as compression molding and subjected to photo⁻aging under ultraviolet (UV) irradiation. The influence of the preparation method, including the casting solvents, as well as the UV irradiation time selected to treat the samples, were evaluated in terms of permeation rates of pure gases (CO₂, N₂, O₂, CH₄, He, and H₂). The transport data were correlated with the microstructure and surface properties by using differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), matrix-assisted laser desorption ionization time-of-flight mass spectrometry (MALDI-TOF MS), as well as water contact angle measurements. The obtained results showed that a controlled photo-oxidation process reduces the hydrophobicity of the Pebax^®2533 films, increasing their permeability without compromising their integrity.

SUBMITTER: Clarizia G

PROVIDER: S-EPMC6119977 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Poly(ether-block-amide) copolymer membrane for CO2/N2 separation: the influence of the casting solution concentration on its morphology, thermal properties and gas separation performance.

Project description:The present work is focused on the study of the effect that the casting solution concentration has on the morphology and gas separation performance of poly(ether-block-amide) copolymer membranes (Pebax® MH 1657). With this aim, three different concentrations of Pebax® MH 1657 in the casting solution (1, 3 and 5 wt%) were used to prepare dense membranes with a thickness of 40 µm. The morphology and thermal stability of all membranes were characterized by scanning electron microscopy, X-ray diffraction, differential scanning calorimetry, rotational viscometry and thermogravimetric analyses. An increase in crystallinity was notable when the amount of solvent in the Pebax® MH 1657 solution was higher, mainly related to the polymer chains arrangement and the solvent evaporation time. Such characteristic seemed to play a key role in the thermal degradation of the membranes, confirming that the most crystalline materials tend to be thermally more stable than those with lower crystallinity. To study the influence of their morphology and operating temperature on the CO2 separation, gas separation tests were conducted with the gas mixture CO2/N2. Results indicated that a compromise must be found between the amount of solvent used to prepare the membranes and the crystallinity, in order to reach the best gas separation performance. In this study, the best performance was achieved with the membrane prepared from a 3 wt% casting solution, reaching at 35°C and under a feed pressure of 3 bar, a CO2 permeability of 110 Barrer and a CO2/N2 selectivity of 36.

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| S-EPMC9954231 | biostudies-literature

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