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Copper-Catalyzed Heteroarylboration of 1,3-Dienes with 3-Bromopyridines: A cine Substitution.

ABSTRACT: A method for the heteroarylboration of 1,3-dienes is presented. The process involves an unusual cine substitution of 3-bromopyridine derivatives to deliver highly functionalized heterocyclic products. Mechanistic studies are included that clarify the details of this unusual process.

SUBMITTER: Smith KB 

PROVIDER: S-EPMC6132256 | biostudies-literature | 2018 May

REPOSITORIES: biostudies-literature

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Copper-Catalyzed Heteroarylboration of 1,3-Dienes with 3-Bromopyridines: A cine Substitution.

Smith Kevin B KB   Huang Yuan Y   Brown M Kevin MK  

Angewandte Chemie (International ed. in English) 20180426 21

A method for the heteroarylboration of 1,3-dienes is presented. The process involves an unusual cine substitution of 3-bromopyridine derivatives to deliver highly functionalized heterocyclic products. Mechanistic studies are included that clarify the details of this unusual process. ...[more]

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