Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

In situ XPS data for the uranyl-modified oxides under visible light.

ABSTRACT: The silica, alumina, ceria, and titania supports were modified with uranyl ions (5?wt%) and investigated using X-ray photoelectron spectroscopy. The data show the U4f photoelectron spectra and charge state of uranium for uranyl ions deposited on different supports. The additional in situ XPS experiments with simultaneous irradiation of the sample using a 450?nm light-emitting diode were performed, and the XPS spectra, revealing a partial reduction of uranium under visible irradiation, are presented. The data show the effect of support material on the chemical states of uranium and oxygen on the surface of uranyl-modified oxides under visible light.

SUBMITTER: Filippov TN

PROVIDER: S-EPMC6141519 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

<i>In situ</i> XPS data for the uranyl-modified oxides under visible light.

Filippov T N TN Kovalevskiy N S NS Solovyeva M I MI Chetyrin I A IA Prosvirin I P IP Lyulyukin M N MN Selishchev D S DS Kozlov D V DV

Data in brief 20180705

The silica, alumina, ceria, and titania supports were modified with uranyl ions (5 wt%) and investigated using X-ray photoelectron spectroscopy. The data show the U4f photoelectron spectra and charge state of uranium for uranyl ions deposited on different supports. The additional <i>in situ</i> XPS experiments with simultaneous irradiation of the sample using a 450 nm light-emitting diode were performed, and the XPS spectra, revealing a partial reduction of uranium under visible irradiation, are ...[more]

PMID: 30229081

Similar Datasets

Direct visible-light-induced synthesis of P-stereogenic phosphine oxides under air conditions.

Project description:Over the past two decades, visible-light-induced transformations have been regarded as being among the most environmentally benign and powerful strategies for constructing complex molecules and diverse synthetic building blocks in organic synthesis. However, the development of efficient photochemical processes for assembling enantiomerically pure molecules remains a significant challenge. Herein, we describe a simple and efficient visible-light-induced C-P bond forming reaction for the synthesis of P-chiral heteroaryl phosphine oxides in moderate to high yields with excellent ee values (97-99% ee). Even in the absence of transition metal or photoredox catalysts, a variety of P-chiral heteroaryl phosphine oxides, including chiral diphosphine oxide 41, have been directly obtained under air conditions. Density functional theory (DFT) calculations have shown that the reaction involves intersystem crossing and single electron transfer to give a diradical intermediate under visible light irradiation.

| S-EPMC9172294 | biostudies-literature

Dual-defect-modified graphitic carbon nitride with boosted photocatalytic activity under visible light.

Project description:The development of photocatalysts that efficiently degrade organic pollutants is an important environmental-remediation objective. To that end, we report a strategy for the ready fabrication of oxygen-doped graphitic carbon nitride (CN) with engendered nitrogen deficiencies. The addition of KOH and oxalic acid during the thermal condensation of urea led to a material that exhibits a significantly higher pseudo-first-order rate constant for the degradation of bisphenol A (BPA) (0.0225 min-1) compared to that of CN (0.00222 min-1). The enhanced photocatalytic activity for the degradation of BPA exhibited by the dual-defect-modified CN (Bt-OA-CN) is ascribable to a considerable red-shift in its light absorption compared to that of CN, as well as its modulated energy band structure and more-efficient charge separation. Furthermore, we confirmed that the in-situ-formed cyano groups in the Bt-OA-CN photocatalyst act as strong electron-withdrawing groups that efficiently separate and transfer photo-generated charge carriers to the surface of the photocatalyst. This study provides novel insight into the in-situ dual-defect strategy for g-C3N4, which is extendable to the modification of other photocatalysts; it also introduces Bt-OA-CN as a potential highly efficient visible-light-responsive photocatalyst for use in environmental-remediation applications.

| S-EPMC6795803 | biostudies-other

The Uranyl Cation as a Visible-Light Photocatalyst for C(sp(3) )-H Fluorination.

Project description:The fluorination of unactivated C(sp(3) )-H bonds remains a desirable and challenging transformation for pharmaceutical, agricultural, and materials scientists. Previous methods for this transformation have used bench-stable fluorine atom sources; however, many still rely on the use of UV-active photocatalysts for the requisite high-energy hydrogen atom abstraction event. Uranyl nitrate hexahydrate is described as a convenient, hydrogen atom abstraction catalyst that can mediate fluorinations of certain alkanes upon activation with visible light.

| S-EPMC5091084 | biostudies-literature

In Situ Preparation of CoP@CdS and Its Catalytic Activity toward Controlling Nitro Reduction under Visible-Light Irradiation.

Project description:CoP was synthesized in situ on the surface of CdS nanowires using a cobalt-ammine complex as a precursor. The generated CoP@CdS photocatalyst was well characterized by X-ray diffraction, transmission electron microscopy, selected-area electron diffraction, and diffuse reflectance spectra. A more efficient charge transfer was successfully achieved owing to the close contact between CoP and CdS. The hybrid photocatalyst showed excellent activity for the reduction of nitroarenes to the corresponding anilines or azobenzene compounds in water. In present work, hydrogen evolution and nitro reduction were concurrent and with the consumption of substrate, the rate of hydrogen evolution increased. The driving force for the reduction originated from the activated hydrogen species in the photocatalytic reaction rather than from dihydrogen. The photocatalytic activity of as-prepared CoP@CdS in situ is comparable to that of the catalysts formed using a noble metal loaded onto CdS. Mechanistic investigation showed that the condensation route is the major pathway for nitro reduction in the present system, and azo compounds could be obtained with less irradiation time, while aniline will be obtained via long-time irradiation.

| S-EPMC6641274 | biostudies-literature

Improved in Situ Synthesis of Heterostructured 2D/2D BiOCl/g-C3N4 with Enhanced Dye Photodegradation under Visible-Light Illumination.

Project description:A simple, in situ, and one-pot hydrothermal strategy was applied for the successful manufacturing of heterostructured 2D/2D BiOCl/g-C3N4 photocatalysts, and outstanding photodegradation of Rhodamine B in the condition of visible-light irradiation over the composites emerged. The investigation of various BiOCl/g-C3N4 ratios influencing the activity implied that the optimized B2C1 (mole ratio of BiOCl/g-C3N4 with 2:1) exhibited the higher degradation efficiency than that of the rest of the composites, even higher than that of pure BiOCl and pure g-C3N4, which yielded over 90% in the initial 30 min and reached almost 100% during the whole 70 min irradiation process. Kinds of characterizations demonstrated that the enhancement of photodegradation performance was caused by the intimate contact between BiOCl and g-C3N4 to form the heterostructure, which could benefit the generation of abundant visible-light photoinduced carriers and help enhance their separation and then promote their transportation to the surface.

| S-EPMC6933762 | biostudies-literature

Degenerative xanthate transfer to olefins under visible-light photocatalysis.

Project description:The degenerative transfer of xanthates to olefins is enabled by the iridium-based photocatalyst [Ir{dF(CF3)ppy}2(dtbbpy)](PF6) under blue LED light irradiation. Detailed mechanistic investigations through kinetics and photophysical studies revealed that the process operates under a radical chain mechanism, which is initiated through triplet-sensitization of xanthates by the long-lived triplet state of the iridium-based photocatalyst.

| S-EPMC6296426 | biostudies-literature

Into the Blue: Ketene Multicomponent Reactions under Visible Light.

Project description:For the first time, a detailed study on the photophysical properties of variously substituted diazoketones and on their photoreactivity under blue LED irradiation was carried out. Despite very limited absorbance in the visible region, we have demonstrated that, independently from their structure, α-diazoketones all undergo a very efficient Wolff rearrangement. Contrarily to the same UV-mediated reaction, where photons can give rise to side processes, in this case, almost all absorbed photons are selective and effective, and the quantum yield is close to 100%. If the rearrangement is carried out in the presence of isocyanides and carboxylic acids/silanols, the photoreactivity is not affected, and the resulting ketenes can afford α-acyloxy- and α-silyloxyacrylamides through two distinct multicomponent reactions, performed both in batch and under continuous flow, with improved selectivity and broader scope. These photoinduced multicomponent reactions can be coupled with other visible-light-mediated transformations, thus increasing the diversity of the molecules obtainable by this approach.

| S-EPMC8154565 | biostudies-literature

Visible-light triggered templated ligation on surface using furan-modified PNAs.

Project description:Oligonucleotide-templated reactions are frequently exploited for target detection in biosensors and for the construction of DNA-based materials and probes in nanotechnology. However, the translation of the specifically used template chemistry from solution to surfaces, with the final aim of achieving highly selective high-throughput systems, has been difficult to reach and therefore, poorly explored. Here, we show the first example of a visible light-triggered templated ligation on a surface, employing furan-modified peptide nucleic acids (PNAs). Tailored photo-oxidation of the pro-reactive furan moiety is ensured by the simultaneous introduction of a weak photosensitizer as well as a nucleophilic moiety in the reacting PNA strand. This allows one to ensure a localized production of singlet oxygen for furan activation, which is not affected by probe dilution or reducing conditions. Simple white light irradiation in combination with target-induced proximity between reactive functionalities upon recognition of a short 22mer DNA or RNA sequence that functions as a template, allows sensitive detection of nucleic acid targets in a 96 well plate format.

| S-EPMC8162948 | biostudies-literature

TiO2 Modified with Organic Acids for the Decomposition of Chlorfenvinphos under the Influence of Visible Light: Activity, Performance, Adsorption, and Kinetics.

Project description:Photocatalytic decomposition of chlorfenvinphos (CFVP) in the presence of titanium dioxide (TiO2) modified with organic acids: pyruvic (PA) and succinic (SA) under the visible light radiation has been studied. The following tests were examined: dose of photocatalysts, adsorption time, pH of the model solution, deactivation of catalysts, the role of oxygen, identification of free radicals for the CFVP decomposition, Langmuir-Hinshelwood kinetics. The synthesized materials were characterized by Scanning Electron Microscopy (SEM) and UV-Vis. At 10 wt.% of acid (90:10) decomposition of chlorfenvinphos was the most effective in the following conditions: dose of catalyst 50.0 mg/L, time of adsorption = 20 min, pH of model solution = 3.0. Under these conditions the order of photocatalyst efficiency has been proposed: TiO2/PA/90:10 > TiO2/SA/90:10 > TiO2 with the removal degree of 85, 72 and 48%. The mathematically calculated half-life at this conditions was 27.0 min and 39.0 min for TiO2/PA/90:10 and TiO2/SA/90:10 respectively, compared to 98 min for pure TiO2. It has been determined that the O2- radicals and holes (h+) are the main reactive species involved in the photodegradation of chlorfenvinphos. The results of this study showed that method may be an interesting alternative for the treatment of chlorfenvinphos contaminated wastewater.

| S-EPMC7013527 | biostudies-literature

Visible Light Photoelectrochemical Sensor for Dopamine: Determination Using Iron Vanadate Modified Electrode.

Project description:This study reports a facile approach for constructing low-cost and remarkable electroactivity iron vanadate (Fe-V-O) semiconductor material to be used as a photoelectrochemical sensor for dopamine detection. The structure and morphology of the iron vanadate obtained by the Successive Ionic Adsorption and Reaction process were critically characterized, and the photoelectrochemical characterization showed a high photoelectroactivity of the photoanode in visible light irradiation. Under best conditions, dopamine was detected by chronoamperometry at +0.35 V vs. Ag/AgCl, achieving two linear response ranges (between 1.21 and 30.32 μmol L-1, and between 30.32 and 72.77 μmol L-1). The limits of detection and quantification were 0.34 and 1.12 μmol L-1, respectively. Besides, the accuracy of the proposed electrode was assessed by determining dopamine in artificial cerebrospinal fluid, obtaining recovery values ranging from 98.7 to 102.4%. The selectivity was also evaluated by dopamine detection against several interferent species, demonstrating good precision and promising application for the proposed method. Furthermore, DFT-based electronic structure calculations were also conducted to help the interpretation. The dominant dopamine species were determined according to the experimental conditions, and their interaction with the iron vanadate photoanode was proposed. The improved light-induced DOP detection was likewise evaluated regarding the charge transfer process.

| S-EPMC9572152 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data