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Degenerative xanthate transfer to olefins under visible-light photocatalysis.

ABSTRACT: The degenerative transfer of xanthates to olefins is enabled by the iridium-based photocatalyst [Ir{dF(CF₃)ppy}₂(dtbbpy)](PF₆) under blue LED light irradiation. Detailed mechanistic investigations through kinetics and photophysical studies revealed that the process operates under a radical chain mechanism, which is initiated through triplet-sensitization of xanthates by the long-lived triplet state of the iridium-based photocatalyst.

SUBMITTER: Kaga A

PROVIDER: S-EPMC6296426 | biostudies-literature | 2018

REPOSITORIES: biostudies-literature

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