Ontology highlight
ABSTRACT:
SUBMITTER: Yamabayashi T
PROVIDER: S-EPMC6152734 | biostudies-literature | 2017 Jun
REPOSITORIES: biostudies-literature
Molecules (Basel, Switzerland) 20170615 6
Single-molecule magnet (SMM) properties of crystals of a terbium(III)-phthalocyaninato double-decker complex with different molecular packings (<b>1</b>: TbPc₂, <b>2</b>: TbPc₂·CH₂Cl₂) were studied to elucidate the relationship between the molecular packing and SMM properties. From single crystal X-ray analyses, the high symmetry of the coordination environment of <b>2</b> suggested that the SMM properties were improved. Furthermore, the shorter intermolecular Tb-Tb distance and relative colline ...[more]