Ontology highlight
ABSTRACT:
SUBMITTER: Nishii K
PROVIDER: S-EPMC6154675 | biostudies-literature | 2017 May
REPOSITORIES: biostudies-literature
Molecules (Basel, Switzerland) 20170502 5
Propene polymerization with isotactic (<i>iso</i>)-specific <i>C</i>₂-symmetric <i>rac</i>-Me₂Si(2-Me-Benz(e)-Ind)₂ZrCl₂ (<b>1</b>) and <i>rac</i>-Me₂Si(2-Me-4-Ph-1-Ind)₂ZrCl₂ (<b>2</b>) were conducted under various conditions for achieving <i>iso</i>-specific living polymerization of propene. When Complex <b>1</b> was activated with trialkylaluminum-free modified methylaluminoxane (dMMAO) at -40 °C, the number-average molecular weight (<i>M</i><sub>n</sub>) linearly increased against the polyme ...[more]