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Asmic: An Exceptional Building Block for Isocyanide Alkylations.

ABSTRACT: Asmic addresses the long-standing challenge of alkylating isocyanides, providing access to isocyanides with diverse substitution patterns. The o-anisylsulfanyl group serves a critical dual role by facilitating deprotonation-alkylation and providing a latent nucleophilic site through an unusual arylsulfanyl-lithium exchange.

SUBMITTER: Alwedi E 

PROVIDER: S-EPMC6172042 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature

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Asmic: An Exceptional Building Block for Isocyanide Alkylations.

Alwedi Embarek E   Lujan-Montelongo J Armando JA   Pitta Bhaskar R BR   Chao Allen A   Cortés-Mejía Rodrigo R   Del Campo Jorge M JM   Fleming Fraser F FF  

Organic letters 20180906 18

Asmic addresses the long-standing challenge of alkylating isocyanides, providing access to isocyanides with diverse substitution patterns. The o-anisylsulfanyl group serves a critical dual role by facilitating deprotonation-alkylation and providing a latent nucleophilic site through an unusual arylsulfanyl-lithium exchange. ...[more]

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