Ontology highlight
ABSTRACT:
SUBMITTER: Wang Z
PROVIDER: S-EPMC6199286 | biostudies-literature | 2018 Oct
REPOSITORIES: biostudies-literature
Wang Zhi Z Su Hai-Feng HF Tung Chen-Ho CH Sun Di D Zheng Lan-Sun LS
Nature communications 20181023 1
The structural transformation of high-nuclearity silver clusters from one to another induced by specific stimuli is of scientific significance in terms of both cluster synthesis and reactivity. Herein, we report two silver-thiolate clusters, [Mo<sub>6</sub>O<sub>22</sub>@Ag<sub>44</sub>] and [Mo<sub>8</sub>O<sub>28</sub>@Ag<sub>50</sub>], which are templated by isopolymolybdates inside and covered by <sup>i</sup>PrS<sup>-</sup> and PhCOO<sup>-</sup> ligands on the surfaces. Amazingly, the [Mo<su ...[more]