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Metal?Organic Framework Thin Film-Based Dye Sensitized Solar Cells with Enhanced Photocurrent.

ABSTRACT: Metal?organic framework thin film-based dye sensitized solar cell is fabricated with highly oriented, crystalline, and porous Zn-perylene metal-organic framework (MOF) thin film (SURMOF) which is integrated with Bodipy embedded in poly(methyl methacrylate). It has been demonstrated that the photocurrent can be enhanced by a factor of 5 relative to Zn-perylene MOF thin film due to triplet?triplet annihilation up-conversion between the Bodipy/PMMA sensitizer and the Zn-perylene MOF thin film acceptor using Co(bpy)?^2+/3+ as redox mediator.

SUBMITTER: Ahmad S

PROVIDER: S-EPMC6213061 | biostudies-literature | 2018 Oct

REPOSITORIES: biostudies-literature

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Metal⁻Organic Framework Thin Film-Based Dye Sensitized Solar Cells with Enhanced Photocurrent.

Ahmad Shargeel S Liu Jinxuan J Ji Wei W Sun Licheng L

Materials (Basel, Switzerland) 20181001 10

Metal⁻organic framework thin film-based dye sensitized solar cell is fabricated with highly oriented, crystalline, and porous Zn-perylene metal-organic framework (MOF) thin film (SURMOF) which is integrated with Bodipy embedded in poly(methyl methacrylate). It has been demonstrated that the photocurrent can be enhanced by a factor of 5 relative to Zn-perylene MOF thin film due to triplet⁻triplet annihilation up-conversion between the Bodipy/PMMA sensitizer and the Zn-perylene MOF thin film accep ...[more]

PMID: 30275372

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