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Spectroscopic studies of amino acid ionic liquid-supported Schiff bases.


ABSTRACT: Amino acid ionic liquid-supported Schiff bases, derivatives of salicylaldehyde and various amino acids (L-threonine, L-valine, L-leucine, L-isoleucine and L-histidine) have been investigated by means of various spectroscopic techniques (NMR, UV-Vis, IR, MS) and deuterium isotope effects on ¹³C-NMR chemical shifts. The results have shown that in all studied amino acid ionic liquid-supported Schiff bases (except the L-histidine derivative) a proton transfer equilibrium exists and the presence of the COO? group stabilizes the proton transferred NH-form.

SUBMITTER: Ossowicz P 

PROVIDER: S-EPMC6269710 | biostudies-literature | 2013 Apr

REPOSITORIES: biostudies-literature

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Spectroscopic studies of amino acid ionic liquid-supported Schiff bases.

Ossowicz Paula P   Janus Ewa E   Schroeder Grzegorz G   Rozwadowski Zbigniew Z  

Molecules (Basel, Switzerland) 20130429 5


Amino acid ionic liquid-supported Schiff bases, derivatives of salicylaldehyde and various amino acids (L-threonine, L-valine, L-leucine, L-isoleucine and L-histidine) have been investigated by means of various spectroscopic techniques (NMR, UV-Vis, IR, MS) and deuterium isotope effects on ¹³C-NMR chemical shifts. The results have shown that in all studied amino acid ionic liquid-supported Schiff bases (except the L-histidine derivative) a proton transfer equilibrium exists and the presence of t  ...[more]

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