Ontology highlight
ABSTRACT:
SUBMITTER: Zou XR
PROVIDER: S-EPMC6300491 | biostudies-literature | 2018
REPOSITORIES: biostudies-literature
Frontiers in chemistry 20181213
Aluminum complexes containing [RP(O)(2-O-3,5-<i>t</i>Bu<sub>2</sub>C<sub>6</sub>H<sub>2</sub>)<sub>2</sub>]<sup>2-</sup> [R = <i>t</i>Bu (<b>3a</b>), Ph (<b>3b</b>)] have been synthesized, structurally characterized, and their reactivity studied in comparison with those of their [RP(2-O-3,5-<i>t</i>Bu<sub>2</sub>C<sub>6</sub>H<sub>2</sub>)<sub>2</sub>]<sup>2-</sup> [R = <i>t</i>Bu (<b>2a</b>), Ph (<b>2b</b>)] analogs. Treating AlMe<sub>3</sub> with one equiv of H<sub>2</sub>[<b>3a-b</b>] in THF ...[more]