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ABSTRACT:
SUBMITTER: Gotsu O
PROVIDER: S-EPMC6321064 | biostudies-literature | 2018 Dec
REPOSITORIES: biostudies-literature
Molecules (Basel, Switzerland) 20181216 12
Intramolecular photocyclization of stilbene derivatives (Mallory reaction) is one of the efficient methods for building polycyclic aromatic hydrocarbon (PAH) frameworks, and is also expected to be applicable to synthesis of fluorine-containing PAHs (F-PAHs). In this study, dibenzoanthracene-type (<b>4a</b>) and benzoperylene-type (<b>4b</b>) F-PAHs were synthesized using the Mallory reaction of the 1,4-distyrylbenzene-type π-conjugated molecule (<b>3a</b>), which was prepared by addition-defluor ...[more]