Ontology highlight
ABSTRACT:
SUBMITTER: Xiong H
PROVIDER: S-EPMC6328574 | biostudies-literature | 2019 Jan
REPOSITORIES: biostudies-literature
Nature communications 20190110 1
Carboazidation of alkenes and alkynes holds the promise to construct valuable molecules directly from chemical feedstock therefore is significantly important. Although a few examples have been developed, there are still some unsolved problems and lack of universal methods for carboazidation of both alkenes and alkynes. Here we describe an iron-catalyzed rapid carboazidation of alkenes and alkynes, enabled by the oxidative radical relay precursor t-butyl perbenzoate. This strategy enjoys success ...[more]