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Metathetical Redox Reaction of (Diacetoxyiodo)arenes and Iodoarenes.

ABSTRACT: The oxidation of iodoarenes is central to the field of hypervalent iodine chemistry. It was found that the metathetical redox reaction between (diacetoxyiodo)arenes and iodoarenes is possible in the presence of a catalytic amount of Lewis acid. This discovery opens a new strategy to access (diacetoxyiodo)arenes. A computational study is provided to rationalize the results observed.

SUBMITTER: Jobin-Des Lauriers A 

PROVIDER: S-EPMC6332457 | biostudies-literature | 2015 Dec

REPOSITORIES: biostudies-literature

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Metathetical Redox Reaction of (Diacetoxyiodo)arenes and Iodoarenes.

Jobin-Des Lauriers Antoine A   Legault Claude Y CY  

Molecules (Basel, Switzerland) 20151217 12

The oxidation of iodoarenes is central to the field of hypervalent iodine chemistry. It was found that the metathetical redox reaction between (diacetoxyiodo)arenes and iodoarenes is possible in the presence of a catalytic amount of Lewis acid. This discovery opens a new strategy to access (diacetoxyiodo)arenes. A computational study is provided to rationalize the results observed. ...[more]

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