Ontology highlight
ABSTRACT:
SUBMITTER: Xiang M
PROVIDER: S-EPMC6339811 | biostudies-literature | 2019 Jan
REPOSITORIES: biostudies-literature
Chemical communications (Cambridge, England) 20190101 7
Highly enantioselective iridium catalyzed carbonyl (2-vinyl)allylation or "isoprenylation" is achieved via hydrogen auto-transfer or 2-propanol-mediated reductive coupling from primary alcohol or aldehyde reactants, respectively. Using this method, asymmetric total syntheses of the terpenoid natural products (+)-ipsenol and (+)-ipsdienol were achieved. ...[more]