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Chemical fuel-driven living and transient supramolecular polymerization.

ABSTRACT: Temporal control over self-assembly process is a desirable trait in the quest towards adaptable and controllable materials. The ability to devise synthetic ways to control the growth, as well as decay of materials has long been a property which only the biological systems could perform seamlessly. A common synthetic strategy which works on the biological principles such as chemical fuel-driven control over temporal self-assembly profile has not been completely realized synthetically. Here we show, we filled this dearth by showing that a chemical fuel driven self-assembling system can not only be grown in a controlled manner, but it can also result in precise control over the assembly and disassembly kinetics. Herein, we elaborate strategies which clearly show that once a chemical fuel driven self-assembly is established it can be made receptive to multiple molecular cues such that the inherent growth and decay characteristics are programmed into the ensemble.

SUBMITTER: Jain A

PROVIDER: S-EPMC6347607 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature

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Chemical fuel-driven living and transient supramolecular polymerization.

Jain Ankit A Dhiman Shikha S Dhayani Ashish A Vemula Praveen K PK George Subi J SJ

Nature communications 20190125 1

Temporal control over self-assembly process is a desirable trait in the quest towards adaptable and controllable materials. The ability to devise synthetic ways to control the growth, as well as decay of materials has long been a property which only the biological systems could perform seamlessly. A common synthetic strategy which works on the biological principles such as chemical fuel-driven control over temporal self-assembly profile has not been completely realized synthetically. Here we sho ...[more]

PMID: 30683874

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