Ontology highlight
ABSTRACT:
SUBMITTER: Gao DW
PROVIDER: S-EPMC6364988 | biostudies-literature | 2018 Apr
REPOSITORIES: biostudies-literature
ACS catalysis 20180321 4
A method to achieve enantioselective 1,4-hydroboration of terminal enynes to access allenyl boronates under CuH catalysis is described. The reaction typically proceeds in a highly stereoselective manner and tolerates an array of synthetically useful functional groups. The utility of the enantioenriched allenyl boronate products is demonstrated through several representative downstream derivatizations. ...[more]