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Synthesis and Characterization of Multiple-Cation Rb(MAFA)PbI₃ Perovskite Single Crystals.

ABSTRACT: We synthesized multiple-cation Rb(MAFA)PbI₃ perovskite single crystals for the first time. The effect of Rb⁺ substitution was systemically investigated, and the addition of 1.5?M 5% RbI was the optimum condition to obtain high-quality Rb(MAFA)PbI₃ single crystals. Lattice shrinkage occurred in the Rb(MAFA)PbI₃ single crystal because of the small ionic radius of Rb⁺, resulting in blue-shifted absorption and photoluminescence (PL) peaks. The 1.5?M 5% RbI-added (MAFA)PbI₃ single crystal showed the longest carrier lifetime of 18.35?ns, exhibiting the highest photoresponse than other crystals. We believe that this work will provide a basic insight into the mixed-cation perovskite single crystals for the future optoelectronic applications.

SUBMITTER: Kim H

PROVIDER: S-EPMC6376001 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature

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Synthesis and Characterization of Multiple-Cation Rb(MAFA)PbI3 Perovskite Single Crystals.

Kim Hyojung H Byun Hye Ryung HR Jeong Mun Seok MS

Scientific reports 20190214 1

We synthesized multiple-cation Rb(MAFA)PbI3 perovskite single crystals for the first time. The effect of Rb+ substitution was systemically investigated, and the addition of 1.5 M 5% RbI was the optimum condition to obtain high-quality Rb(MAFA)PbI3 single crystals. Lattice shrinkage occurred in the Rb(MAFA)PbI3 single crystal because of the small ionic radius of Rb+, resulting in blue-shifted absorption and photoluminescence (PL) peaks. The 1 ...[more]

PMID: 30765856

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