Ontology highlight
ABSTRACT:
SUBMITTER: Usuki T
PROVIDER: S-EPMC6384591 | biostudies-literature | 2019 Jan
REPOSITORIES: biostudies-literature
Molecules (Basel, Switzerland) 20190131 3
A series of disilane-linked donor‒acceptor‒donor triads (D‒Si‒Si‒A‒Si‒Si‒D) was synthesized to investigate the effects of substituents on the photophysical properties. The triads were prepared by metal-catalyzed diiodosilylation of aryl iodides using a Pd(P(<i>t</i>-Bu)₃)₂/(<i>i</i>-Pr)₂EtN/toluene system that we previously developed. Optical measurements, X-ray diffraction analysis, and density functional theory calculations revealed relationships between the photophysical properties and molecu ...[more]