Ontology highlight
ABSTRACT:
SUBMITTER: Kelber JB
PROVIDER: S-EPMC6054115 | biostudies-literature | 2015 Nov
REPOSITORIES: biostudies-literature
Kelber Julien B JB Panjwani Naitik A NA Wu Di D Gómez-Bombarelli Rafael R Lovett Brendon W BW Morton John J L JJL Anderson Harry L HL
Chemical science 20150731 11
Two donor-porphyrin-acceptor triads have been synthesized using a versatile Suzuki-coupling route. This synthetic strategy allows the powerful donor tetraalkylphenylenediamine (<b>TAPD</b>) to be introduced into tetraarylporphyrin-based triads without protection. The thermodynamics and kinetics of electron transfer in the new triads are compared with a previously reported octaalkyldiphenyl-porphyrin triad exhibiting a long-lived spin-polarized charge separate state (CSS), from theoretical and ex ...[more]