Dataset Information

Synergetic Toughening Effect of Carbon Nanotubes and ?-Nucleating Agents on the Polypropylene Random Copolymer/Styrene-Ethylene-Butylene- Styrene Block Copolymer Blends.

ABSTRACT: Polypropylene random co-polymer (PPR)/styrene-ethylene-butylene-styrene (SBS) block copolymer blends with high toughness and favorable tensile properties were successfully obtained by blending with traces of multi-wall carbon nanotubes (MWCNTs) and ?-nucleating agents (?-NAs). ?-NAs can effectively induce the ductile ?-form crystal in the PPR matrix. Although the addition of MWCNTs was reported to be only benefit for the tensile strength of PPR and relatively disadvantageous for the toughness, the obviously synergistic toughening effect in PPR/SBS blends was found when MWCNTs and ?-NAs coexisted. The notched izod impact strength of PPR/30 wt % SBS blend with MWCNTs and ?-NAs increased from 11.3 to 58.9 kJ/m²; more than 5-fold increment compared with pure PPR. Meanwhile, the tensile strength retention of this PPR blend is still above 72.2%. The micro-morphology indicated that the MWCNTs can act as bridges between SBS particle and PPR matrix, effectively transferring the stress and absorbing impact energy among SBS particles.

SUBMITTER: Ren PG

PROVIDER: S-EPMC6401747 | biostudies-literature | 2018 Dec

REPOSITORIES: biostudies-literature

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Synergetic Toughening Effect of Carbon Nanotubes and β-Nucleating Agents on the Polypropylene Random Copolymer/Styrene-Ethylene-Butylene- Styrene Block Copolymer Blends.

Ren Peng-Gang PG Wang Jin J Fan Qian Q Yang Song S Wu Zhi-Qiang ZQ Yan Ding-Xiang DX Chen Yan-Hui YH

Polymers 20181226 1

Polypropylene random co-polymer (PPR)/styrene-ethylene-butylene-styrene (SBS) block copolymer blends with high toughness and favorable tensile properties were successfully obtained by blending with traces of multi-wall carbon nanotubes (MWCNTs) and β-nucleating agents (β-NAs). β-NAs can effectively induce the ductile β-form crystal in the PPR matrix. Although the addition of MWCNTs was reported to be only benefit for the tensile strength of PPR and relatively disadvantageous for the toughness, t ...[more]

PMID: 30960013

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Project description:Scaffolds from poly(ethylene oxide) and poly(butylene terephthalate), PEOT/PBT, with a PEO molecular weight of 1,000 and a PEOT content of 70 weight% (1000PEOT70PBT30) were prepared by leaching salt particles (425-500 microm). Scaffolds of 73.5, 80.6 and 85.0% porosity were treated with a CO(2) gas plasma and seeded with rat bone marrow stromal cells (BMSCs). After in vitro culture for 7 days (d) in an osteogenic medium the scaffolds were subcutaneously implanted for 4 weeks in nude mice. Poly(D, L-lactide) (PDLLA) and biphasic calcium phosphate (BCP) scaffolds were included as references. After 4 weeks (wks) all scaffolds showed ectopic formation of bone and bone marrow. For the scaffolds of different porosities, no significant differences were observed in the relative amounts of bone (7-9%) and bone marrow (6-11%) formed, even though micro computed tomography (mu-CT) data showed considerable differences in accessible pore volume and surface area. 1000PEOT70PBT30 scaffolds with a porosity of 85% could not maintain their original shape in vivo. Surprisingly, 1000PEOT70PBT30 scaffolds with a porosity of 73.5% showed cartilage formation. This cartilage formation is most likely due to poorly accessible pores in the scaffolds, as was observed in histological sections. mu-CT data showed a considerably smaller accessible pore volume (as a fraction of the total volume) than in 1000PEOT70PBT30 scaffolds of 80.6 and 85.0% porosity. BMSC seeded PDLLA (83.5% porosity) and BCP scaffolds (29% porosity) always showed considerably more bone and bone marrow formation (bone marrow formation is approximately 40%) and less fibrous tissue ingrowth than the 1000PEOT70PBT30 scaffolds. The scaffold material itself can be of great influence. In more hydrophobic and rigid scaffolds like the PDLLA or BCP scaffolds, the accessibility of the pore structure is more likely to be preserved under the prevailing physiological conditions than in the case of hydrophilic 1000PEOT70PBT30 scaffolds. Scaffolds prepared from other PEOT/PBT polymer compositions, might prove to be more suited.

Dataset Information

Synergetic Toughening Effect of Carbon Nanotubes and ?-Nucleating Agents on the Polypropylene Random Copolymer/Styrene-Ethylene-Butylene- Styrene Block Copolymer Blends.

Publications

Synergetic Toughening Effect of Carbon Nanotubes and β-Nucleating Agents on the Polypropylene Random Copolymer/Styrene-Ethylene-Butylene- Styrene Block Copolymer Blends.

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