Morphological Structure, Rheological Behavior, Mechanical Properties and Sound Insulation Performance of Thermoplastic Rubber Composites Reinforced by Different Inorganic Fillers.
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ABSTRACT:
SUBMITTER: Fei Y
PROVIDER: S-EPMC6414929 | biostudies-literature |
REPOSITORIES: biostudies-literature
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Project description:Reinforcement of flexible fibre reinforced plastic (FRP) composites with standard textile fibres is a potential low cost solution to less critical loading applications. The mechanical behaviour of FRPs based on mechanically bonded nonwoven preforms composed of either low or high modulus fibres in a thermoplastic polyurethane (TPU) matrix were compared following compression moulding. Nonwoven preform fibre compositions were selected from lyocell, polyethylene terephthalate (PET), polyamide (PA) as well as para-aramid fibres (polyphenylene terephthalamide; PPTA). Reinforcement with standard fibres manifold improved the tensile modulus and strength of the reinforced composites and the relationship between fibre, fabric and composite's mechanical properties was studied. The linear density of fibres and the punch density, a key process variable used to consolidate the nonwoven preform, were varied to study the influence on resulting FRP mechanical properties. In summary, increasing the strength and degree of consolidation of nonwoven preforms did not translate to an increase in the strength of resulting fibre reinforced TPU-composites. The TPU composite strength was mainly dependent upon constituent fibre stress-strain behaviour and fibre segment orientation distribution.
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Project description:In additive manufacturing (AM), thermoplastic components made by fused deposition modeling (FDM) offer low strength and stiffness, as required for fully functional and load-bearing parts. Composite materials are a practical solution to improve mechanical properties [1,2]. A new technology to reinforce thermoplastics with continuous fibers has been developed recently by Markforged [3]. It introduces continuous fiber to reinforce a thermoplastic matrix, thus, taking static mechanical performance close to Aluminum alloys [4]. These printers for continuous fiber reinforced thermoplastic composites (CFRTPC) have taken this technology to a whole new level in terms of mechanical properties and efficient production. Mechanical properties under monotonic load were studied for different kinds of printing configurations. Tensile monotonic tests under controlled displacement were performed until rupture. Raw data showing tensile monotonic behavior provides the researchers with the ability to perform data fitting, to validate more advanced constitutive models, or to perform a further interpretation of the data, among others. Data is presented here as plain text files without any analysis. A preliminary data analysis has been published already in [5]. The text files contain information about time, displacement, and force. The data is useful for design engineers and researchers involved with AM.
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Project description:Thermoplastic composites consisting of a liquid crystalline polymer (LCP) and poly(lactide) (PLA) have the potential to combine good mechanical performance with recyclability and are therefore interesting as strong and sustainable composite materials. The viscoelastic behavior of both the LCP and the PLA is of great importance for the performance of these composites, as they determine the LCP morphology in the composite and play a crucial role in preventing the loss of mechanical performance upon recycling. Though the effect of the matrix viscosity is well-documented in literature, well-controlled systems where the LCP viscosity is tailored are not reported. Therefore, four LCPs, with the same chemical backbone but different molecular weights, are used to produce reinforced LCP-PLA composites. The differences in viscosity of the LCPs and viscosity ratio between the dispersed phase and the matrix of the blends are evident in the resultant composite morphology: in all cases fibrils are formed; however, the diameter increases considerably as the viscosity ratio increases for the higher molar mass LCPs. The fibril diameter ranges from several hundred nanometer to a few micrometer. A typical layered structure in the injection molded composites is observed, where the layer-thickness is influenced by the LCP viscosity. The LCPs are found to effectively reinforce the PLLA matrix, increasing the Young's modulus by 60% and the maximum stress by 40% for the composite containing 30 wt % of the most viscous LCP. Remarkably, this did not result in an increase in brittleness, effectively increasing the toughness of the composite compared to pure PLLA. The feasible reprocessability of this composite is confirmed, by subjecting it to three reprocessing cycles. The relaxation of the LCPs orientation upon heating is measured via in situ WAXD. We compare the relaxation in an amorphous PLA matrix and in a semicrystalline PLLA matrix with that of the pure LCPs. The matrix viscosity is found to strongly influence the relaxation. For example, in a low viscous amorphous matrix relaxation of the LCP fibrils into droplets dominates the process, whereas a semicrystalline matrix helps in maintaining the fibril morphology and intermolecular orientation of the LCP. In the latter case, the LCPs relax via contraction and coalescence of the polydomain texture and maintains a significant degree of orientation until the PLLA crystals melt and the matrix viscosity decreases. The insights gained in this study on the role of the LCP viscosity on the morphology and performance of thermoplastic composites, as well as the relaxation of LCPs in a matrix, will aid progression toward sustainable and reprocessable LCP reinforced thermoplastic composites.
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Project description:The effect of individual and combined talc and glass fibers (GFs) on mechanical and thermal expansion performance of the filled high density polyethylene (HDPE) composites was studied. Several published models were adapted to fit the measured tensile modulus and strength of various composite systems. It was shown that the use of silane-modified GFs had a much larger effect in improving mechanical properties and in reducing linear coefficient of thermal expansion (LCTE) values of filled composites, compared with the use of un-modified talc particles due to enhanced bonding to the matrix, larger aspect ratio, and fiber alignment for GFs. Mechanical properties and LCTE values of composites with combined talc and GF fillers varied with talc and GF ratio at a given total filler loading level. The use of a larger portion of GFs in the mix can lead to better composite performance, while the use of talc can help lower the composite costs and increase its recyclability. The use of 30 wt % combined filler seems necessary to control LCTE values of filled HDPE in the data value range generally reported for commercial wood plastic composites. Tensile modulus for talc-filled composite can be predicted with rule of mixture, while a PPA-based model can be used to predict the modulus and strength of GF-filled composites.
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Project description:This paper presents a pioneering effort to ascertain the suitability of hyperelastic modelling in simulating the stress-strain response of oil palm shell reinforced rubber (ROPS) composites. ROPS composites with different oil palm shell contents (0%, 5%, 10% and 20% by volume) were cast in the laboratory for the experimental investigation. ROPS specimens with circular, square, hexagon, and octagon shapes (loading surface) were considered to evaluate the accuracy of finite element simulation considering the shape effect of composites. Strain-controlled (compressive) tests with ? ? 50% at 0.8 Hz frequency were conducted in the laboratory and the test data obtained was used as input to simulate material coefficients corresponding to the strain energy functions chosen. Five different strain energy functions were selected and utilized for the hyperelastic modelling in this study using finite element approach. The shape effect was then used to ascertain any variation in the simulation outcomes and to discuss the effect of shape on the behaviour of ROPS composites in comparison to existing literature. The numerical predictions using the Yeoh model (error ? 2.7% for circular shaped ROPS) were found to perform best in comparison with the experimental results, thus a more stable and suitable hyperelastic model to this end. The Marlow (error ? 4.6% for circular shaped ROPS) and Arruda Boyce (error ? 4.7% for circular shaped ROPS) models were amongst the next alternatives to perform better. Even with the other shapes considered in this study, Yeoh, followed by the Marlow function, were more appropriate models. The shape effect was then studied with particular emphasis on comparing and assessing them with that observed in the literature. To this end, adopting the Yeoh function in the finite element model is the ideal approach to estimate the stress-strain response of ROPS composites.
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Project description:Reprocessing of reinforced composites is generally accompanied by loss of value and performance, as normally the reinforcing phase is damaged, or the matrix is lost in the process. In the search for more sustainable recyclable composite materials, we identify blends based on poly(l-lactide) (PLA) and thermotropic liquid crystalline polymers (LCP) as highly promising self-reinforced thermoplastic composites that can be recycled several times without loss in mechanical properties. For example, irrespective of the thermal history of the blend, injection molded bars of PLA containing 30 wt % LCP exhibit a tensile modulus of 6.4 GPa and tensile strength around 110 MPa, as long as the PLA matrix has a molecular weight of 170 kg mol-1 or higher. However, after several mechanical reprocessing steps, with the gradual decrease in the molecular weight of the PLA matrix, deterioration of the mechanical performance is observed. The origin of this behavior is found in the increasing LCP to PLA viscosity ratio: at a viscosity ratio below unity, the dispersed LCP droplets are effectively deformed into the desired fibrillar morphology during injection molding. However, deformation of LCP droplets becomes increasingly challenging when the viscosity ratio exceeds unity (i.e., when the PLA matrix viscosity decreases during consecutive reprocessing), eventually resulting in a nodular morphology, a poor molecular orientation of the LCP phase, and deterioration of the mechanical performance. This molecular weight dependency effectively places a limit on the maximum number of mechanical reprocessing steps before chemical upgrading of the PLA phase is required. Therefore, a feasible route to maintain or enhance the mechanical properties of the blend, independent of the number of reprocessing cycles, is proposed.
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