Dataset Information

Near-Infrared Light and Solar Light Activated Self-Healing Epoxy Coating having Enhanced Properties Using MXene Flakes as Multifunctional Fillers.

ABSTRACT: Two issues are required to be solved to bring intrinsically self-healing polymer coatings into real applications: remote activation and satisfied practical properties. Here, we used MXene, a newly reported two-dimensional material, to provide an epoxy coating with light-induced self-healing capabilities and we worked to enhance the properties of that coating. The self-healing coatings had a reversible crosslinking network based on the Diels-Alder reaction among maleimide groups from bis(4-maleimidopheny)methane and dangling furan groups in oligomers that were prepared through the condensation polymerization of diglycidylether of bisphenol A and furfurylamine. The results showed that the delaminated MXene flakes were small in size, around 900 nm, and dispersed well in self-healing coatings. The MXene flakes of only 2.80 wt % improved greatly the pencil hardness of the coating hardness from HB to 5H and the polarization resistance from 4.3 to 428.3 M? cm^-2. The self-healing behavior, however, was retarded by MXene flakes. Leveling agent acted a key part here to facilitate the gap closure driven by reverse plasticity to compensate for the limitation of macromolecular mobility resulting from the MXene flakes. The self-healing of coatings was achieved in 30 s by thermal treatment at 150 °C. The efficient self-healing was also demonstrated based on the recovery of the anti-corrosion capability. MXene flakes also played an evident photothermal role in generating heat via irradiation of near-infrared light at 808 nm and focused sunlight. The healing can be quickly obtained in 10 s under irradiation of near-infrared light at 808 nm having a power density of 6.28 W cm^-2 or in 10 min under irradiation of focused sunlight having a power density of 4.0 W cm^-2.

SUBMITTER: Zou Y

PROVIDER: S-EPMC6415427 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Near-Infrared Light and Solar Light Activated Self-Healing Epoxy Coating having Enhanced Properties Using MXene Flakes as Multifunctional Fillers.

Zou Yuting Y Fang Liang L Chen Tianqi T Sun Menglong M Lu Chunhua C Xu Zhongzi Z

Polymers 20180426 5

Two issues are required to be solved to bring intrinsically self-healing polymer coatings into real applications: remote activation and satisfied practical properties. Here, we used MXene, a newly reported two-dimensional material, to provide an epoxy coating with light-induced self-healing capabilities and we worked to enhance the properties of that coating. The self-healing coatings had a reversible crosslinking network based on the Diels-Alder reaction among maleimide groups from bis(4-maleim ...[more]

PMID: 30966508

Similar Datasets

Project description:A series of composites based on epoxy resin filled with additives of natural origin were prepared to investigate the influence of such fillers on the properties of the epoxy compositions. For this purpose, the composites containing 5 and 10 wt.% of additive of natural origin were obtained using the dispersion of oak wood waste and peanut shells in bisphenol A epoxy resin cured with isophorone-diamine. The oak waste filler had been obtained during the assembly of the raw wooden floor. The performed studies include testing of samples prepared using unmodified and chemically modified additives. Chemical modification via mercerization and silanization was performed to increase the poor compatibility between the highly hydrophilic fillers of natural origin and the hydrophobic polymer matrix. Additionally, the introduction of NH2 groups to the structure of modified filler via 3-aminopropyltriethoxysilane, potentially takes a part in co-crosslinking with the epoxy resin. Fourier Transformed Infrared Spectroscopy (FT-IR), as well as Scanning Electron Microscopy (SEM), were carried out, to study the influence of performed chemical modification on the chemical structure and morphology of wood and peanut shell flour. SEM analyses showed significant changes in the morphology of compositions with chemically modified fillers, indicating improved adhesion of the resin to lignocellulosic waste particles. Moreover, a series of mechanical (hardness, tensile strength, flexural strength, compressive strength, and impact strength) tests were carried out, to assess the influence of the application of fillers of natural origin on the properties of epoxy compositions. All composites with lignocellulosic filler were characterized by higher compressive strength (64.2 MPa-5%U-OF, 66.4%-SilOF, 63.2-5%U-PSF, and 63.8-5%SilPSF, respectively), compared to the values recorded for the reference epoxy composition without lignocellulosic filler (59.0 MPa-REF). The highest compressive strength, among all tested samples, was recorded for the composite filled with 10 wt.% of unmodified oak flour (69.1 MPa-10%U-OF). Additionally, higher values of flexural and impact strength, concerning pure BPA-based epoxy resin, were recorded for the composites with oak filler (respectively, flexural strength: 73.8 MPa-5%U-OF and 71.5 MPa-REF; impact strength: 15.82 kJ/m2-5%U-OF, 9.15 kJ/m2-REF). Epoxy composites with such mechanical properties might be considered as broadly understood construction materials. Moreover, samples containing wood flour as a filler exhibit better mechanical properties compared to those with peanut shell flour (tensile strength for samples containing post-mercerization filler: 48.04 MPa and 40.54 MPa; while post-silanization 53.53 MPa and 42.74 MPa for compositions containing 5 wt.% of wood and peanut shell flour, respectively). At the same time, it was found that increasing the weight share of flour of natural origin in both cases resulted in the deterioration of mechanical properties.

Dataset Information

Near-Infrared Light and Solar Light Activated Self-Healing Epoxy Coating having Enhanced Properties Using MXene Flakes as Multifunctional Fillers.

Publications

Near-Infrared Light and Solar Light Activated Self-Healing Epoxy Coating having Enhanced Properties Using MXene Flakes as Multifunctional Fillers.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets