Dataset Information
Thermoinduced structural-transformation and thermochromic luminescence in organic manganese chloride crystals.
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ABSTRACT:
SUBMITTER: Sun ME
PROVIDER: S-EPMC6457203 | biostudies-literature | 2019 Apr
REPOSITORIES: biostudies-literature
Publications
Thermoinduced structural-transformation and thermochromic luminescence in organic manganese chloride crystals.
Chemical science 20190225 13
The [Mn<sub>2</sub>Cl<sub>9</sub>]<sup>5-</sup> mode of red emissive (C<sub>4</sub>NOH<sub>10</sub>)<sub>5</sub>Mn<sub>2</sub>Cl<sub>9</sub>·C<sub>2</sub>H<sub>5</sub>OH under thermal treatment will be cleaved into [MnCl<sub>4</sub>]<sup>2-</sup> in the green emissive (C<sub>4</sub>NOH<sub>10</sub>)<sub>2</sub>MnCl<sub>4</sub> with the departure of ethanol. The rapid conversion of luminescence from red to green provides new insight into the luminescence origin and thermal stability of organic-in ...[more]