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Thermoinduced structural-transformation and thermochromic luminescence in organic manganese chloride crystals.

ABSTRACT: The [Mn₂Cl₉]^5- mode of red emissive (C₄NOH₁₀)₅Mn₂Cl₉·C₂H₅OH under thermal treatment will be cleaved into [MnCl₄]^2- in the green emissive (C₄NOH₁₀)₂MnCl₄ with the departure of ethanol. The rapid conversion of luminescence from red to green provides new insight into the luminescence origin and thermal stability of organic-inorganic metal halide hybrids.

SUBMITTER: Sun ME

PROVIDER: S-EPMC6457203 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature

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Thermoinduced structural-transformation and thermochromic luminescence in organic manganese chloride crystals.

Sun Meng-En ME Li Yao Y Dong Xi-Yan XY Zang Shuang-Quan SQ

Chemical science 20190225 13

The [Mn2Cl9]5- mode of red emissive (C4NOH10)5Mn2Cl9·C2H5OH under thermal treatment will be cleaved into [MnCl4]2- in the green emissive (C4NOH10)2MnCl4 with the departure of ethanol. The rapid conversion of luminescence from red to green provides new insight into the luminescence origin and thermal stability of organic-in ...[more]

PMID: 31015925

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