Atomically defined angstrom-scale all-carbon junctions.

ABSTRACT: Full-carbon electronics at the scale of several angstroms is an expeimental challenge, which could be overcome by exploiting the versatility of carbon allotropes. Here, we investigate charge transport through graphene/single-fullerene/graphene hybrid junctions using a single-molecule manipulation technique. Such sub-nanoscale electronic junctions can be tuned by band gap engineering as exemplified by various pristine fullerenes such as C₆₀, C₇₀, C₇₆ and C₉₀. In addition, we demonstrate further control of charge transport by breaking the conjugation of their ? systems which lowers their conductance, and via heteroatom doping of fullerene, which introduces transport resonances and increase their conductance. Supported by our combined density functional theory (DFT) calculations, a promising future of tunable full-carbon electronics based on numerous sub-nanoscale fullerenes in the large family of carbon allotropes is anticipated.

SUBMITTER: Tan Z 

PROVIDER: S-EPMC6465289 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature