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In-situ X-Ray Absorption Near Edge Structure Spectroscopy of a Solid Catalyst using a Laboratory-Based Set-up.

ABSTRACT: An in-situ laboratory-based X-ray Absorption Near Edge Structure (XANES) Spectroscopy set-up is presented, which allows performing long-term experiments on a solid catalyst at relevant reaction conditions of temperature and pressure. Complementary to research performed at synchrotron radiation facilities the approach is showcased for a Co/TiO₂ Fischer-Tropsch Synthesis (FTS) catalyst. Supported cobalt metal nanoparticles next to a (very small) fraction of cobalt(II) titanate, which is an inactive phase for FTS, were detected, with no signs of re-oxidation of the supported cobalt metal nanoparticles during FTS at 523?K, 5?bar and 200?h, indicating that cobalt metal is maintained as the main active phase during FTS.

SUBMITTER: Moya-Cancino JG

PROVIDER: S-EPMC6471006 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature

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In-situ X-Ray Absorption Near Edge Structure Spectroscopy of a Solid Catalyst using a Laboratory-Based Set-up.

Moya-Cancino José G JG Honkanen Ari-Pekka AP van der Eerden Ad M J AMJ Schaink Herrick H Folkertsma Lieven L Ghiasi Mahnaz M Longo Alessandro A de Groot Frank M F FMF Meirer Florian F Huotari Simo S Weckhuysen Bert M BM

ChemCatChem 20190111 3

An in-situ laboratory-based X-ray Absorption Near Edge Structure (XANES) Spectroscopy set-up is presented, which allows performing long-term experiments on a solid catalyst at relevant reaction conditions of temperature and pressure. Complementary to research performed at synchrotron radiation facilities the approach is showcased for a Co/TiO2 Fischer-Tropsch Synthesis (FTS) catalyst. Supported cobalt metal nanoparticles next to a (very small) fraction of cobalt(II) titanate, w ...[more]

PMID: 31007776

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