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Facile Fabrication of Magnetic, Durable and Superhydrophobic Cotton for Efficient Oil/Water Separation.

ABSTRACT: In this paper, we present a facile and efficient strategy for the fabrication of magnetic, durable, and superhydrophobic cotton for oil/water separation. The superhydrophobic cotton functionalized with Fe?O? magnetic nanoparticles was prepared via the in situ coprecipitation of Fe²⁺/Fe³⁺ ions under ammonia solution on cotton fabrics using polyvinylpyrrolidone (PVP) as a coupling agent and hydrophobic treatment with tridecafluorooctyl triethoxysilane (FAS) in sequence. The as-prepared cotton demonstrated excellent superhydrophobicity with a water contact angle of 155.6° ± 1.2° and good magnetic responsiveness. Under the control of the external magnetic field, the cotton fabrics could be easily controlled to absorb the oil from water as oil absorbents, showing high oil/water separation efficiency, even in hot water. Moreover, the cotton demonstrated remarkable mechanical durable properties, being strongly friction-resistant against sandpaper and finger wipe, while maintaining its water repellency. This study developed a novel and efficient strategy for the construction of magnetic, durable, and superhydrophobic biomass-based adsorbent for oil/water separation, which can be easily scaled up for practical oil absorption.

SUBMITTER: Yu M

PROVIDER: S-EPMC6473410 | biostudies-literature | 2019 Mar

REPOSITORIES: biostudies-literature

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Facile Fabrication of Magnetic, Durable and Superhydrophobic Cotton for Efficient Oil/Water Separation.

Yu Mingguang M Wang Qing Q Yang Wenxin W Xu Yonghang Y Zhang Min M Deng Qianjun Q Liu Guang G

Polymers 20190307 3

In this paper, we present a facile and efficient strategy for the fabrication of magnetic, durable, and superhydrophobic cotton for oil/water separation. The superhydrophobic cotton functionalized with Fe₃O₄ magnetic nanoparticles was prepared via the in situ coprecipitation of Fe<sup>2+</sup>/Fe<sup>3+</sup> ions under ammonia solution on cotton fabrics using polyvinylpyrrolidone (PVP) as a coupling agent and hydrophobic treatment with tridecafluorooctyl triethoxysilane (FAS) in sequence. The a ...[more]

PMID: 30960426

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Project description:The fluoride-free fabrication of superhydrophobic materials for the separation of oil/water mixtures has received widespread attention because of frequent offshore oil exploration and chemical leakage. In recent years, oil/water separation materials, based on metal meshes, have drawn much attention, with significant advantages in terms of their high mechanical strength, easy availability, and long durability. However, it is still challenging to prepare superhydrophobic metal meshes with high-separation capacity, low costs, and high recyclability for dealing with oil-water separation. In this work, a superhydrophobic and super oleophilic stainless steel mesh (SSM) was successfully prepared by anchoring Fe2O3 nanoclusters (Fe2O3-NCs) on SSM via the in-situ flame synthesis method and followed by further modification with octadecyltrimethoxysilane (OTS). The as-prepared SSM with Fe2O3-NCs and OTS (OTS@Fe2O3-NCs@SSM) was confirmed by a field emission scanning electron microscope (FESEM), transmission electron microscope (TEM), energy dispersive spectrometer (EDS), X-ray photoelectron spectrometer (XPS), and X-ray diffractometer (XRD). The oil-water separation capacity of the sample was also measured. The results show that the interlaced and dense Fe2O3-NCs, composed of Fe2O3 nanoparticles, were uniformly coated on the surface of the SSM after the immerging-burning process. Additionally, a compact self-assembled OTS layer with low surface energy is coated on the surface of Fe2O3-NCs@SSM, leading to the formation of OTS@Fe2O3-NCs@SSM. The prepared OTS@Fe2O3-NCs@SSM shows excellent superhydrophobicity, with a water static contact angle of 151.3°. The separation efficiencies of OTS@Fe2O3-NCs@SSM for the mixtures of oil/water are all above 98.5%, except for corn oil/water (97.5%) because of its high viscosity. Moreover, the modified SSM exhibits excellent stability and recyclability. This work provides a facile approach for the preparation of superhydrophobic and super oleophilic metal meshes, which will lead to advancements in their large-scale applications on separating oil/water mixtures.

Dataset Information

Facile Fabrication of Magnetic, Durable and Superhydrophobic Cotton for Efficient Oil/Water Separation.

Publications

Facile Fabrication of Magnetic, Durable and Superhydrophobic Cotton for Efficient Oil/Water Separation.

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