Browse
Submit Data
Databases
API
Help

Dataset Information

25 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

One-Step Low Temperature Hydrothermal Synthesis of Flexible TiO₂/PVDF@MoS₂ Core-Shell Heterostructured Fibers for Visible-Light-Driven Photocatalysis and Self-Cleaning.

ABSTRACT: Novel flexible and recyclable core-shell heterostructured fibers based on cauliflower-like MoS₂ and TiO₂/PVDF fibers have been designed through one-step hydrothermal treatment based on electrospun tetrabutyl orthotitanate (TBOT)/PVDF fibers. The low hydrothermal temperature avoids the high temperature process and keeps the flexibility of the as-synthesized materials. The formation mechanism of the resultant product is discussed in detail. The composite of MoS₂ not only expands the light harvesting window to include visible light, but also increases the separation efficiency of photo-generated electrons and holes. The as-prepared product has proven to possess excellent and stable photocatalytic activity in the degradation of Rhodamine B and levofloxacin hydrochloride under visible light irradiation. In addition, the TiO₂/PVDF@MoS₂ core-shell heterostructured fibers exhibit self-cleaning property to dye droplets under visible light irradiation. Meanwhile, due to its hydrophobicity, the resultant product can automatically remove dust on its surface under the rolling condition of droplets. Hence, the as-prepared product cannot only degrade the contaminated compounds on the surface of the material, but also reduce the maintenance cost of the material due to its self-cleaning performance. Therefore, the as-prepared product possesses potential applications in degradation of organic pollutants and water treatment, which makes it a prospective material in the field of environmental treatment.

SUBMITTER: Zhang ZG

PROVIDER: S-EPMC6473952 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Core-Shell Heterostructured and Visible-Light-Driven Titanoniobate/TiO2 Composite for Boosting Photodegradation Performance.

Project description:Herein, we report a one-dimensional (1D) S-doped K3Ti5NbO14@TiO2 (STNT) core-shell heterostructured composite with an enhanced photocatalytic degradation activity under visible light, which was prepared by a simple reassembly-calcination method using thiourea as the S source. The anisotropically shaped rods are favorable for the rapid transport of photogenerated charge carriers. The substitution of Ti4+ by S6+ is primarily incorporated into the lattice of the TiO2 shell so as to create an intra-band-gap state below the conduction band (CB) position, giving rise to Ti-O-S bonds and thus the visible light response. The presence of electron-deficient S atoms is of benefit to the decreased recombination rate of photogenerated electrons and holes by capturing electrons (e-). Meanwhile, a tight close interface between K3Ti5NbO14 and TiO2 was formed to achieve a nano-heterojunction structure, leading to the fostered separation of its interfacial photogenerated electrons and holes. The visible-light-driven photocatalytic degradation of methylene blue (MB) by STNT composites is higher than that by pure K3Ti5NbO14, owing to the synergistic effects of S doping and heterojunction. A possible photocatalytic mechanism was proposed with a reasonable discussion. This work may provide an insight into constructing highly efficient core-shell photocatalysts used toward sustainable environmental remediation and resource shortages.

| S-EPMC6836207 | biostudies-literature

Short-Time Hydrothermal Synthesis of CuBi2O4 Nanocolumn Arrays for Efficient Visible-Light Photocatalysis.

Project description:In this article, a short-time hydrothermal method is developed to prepare CuBi2O4 nanocolumn arrays. By using Bi(NO3)3·5H2O in acetic acid and Cu(NO3)2·3H2O in ethanol as precursor solutions, tetragonal CuBi2O4 with good visible light absorption can be fabricated within 0.5 h at 120 °C. Tetragonal structured CuBi2O4 can be formed after 15 min hydrothermal treatment, however it possesses poor visible light absorption and low photocatalytic activity. Extending the hydrothermal treatment duration to 0.5 h results in a significant improvement invisible light absorption of the tetragonal CuBi2O4. The CuBi2O4 obtained through 0.5 h hydrothermal synthesis shows a band gap of 1.75 eV and exhibits the highest photocatalytic performance among the CuBi2O4 prepared with various hydrothermal time. The removal rate of methylene blue by the 0.5 h CuBi2O4 reaches 91% under visible light irradiation for 0.5 h. This study proposes a novel strategy to prepare photoactive CuBi2O4 nanocolumn arrays within 0.5 h at a moderate temperature of 120 °C. The hydrothermal method provides a facile strategy for the fast synthesis of metal-oxide-based photocatalysts at mild reaction conditions.

| S-EPMC6780588 | biostudies-literature

Mechano-synthesized orange TiO2 shows significant photocatalysis under visible light.

Project description:Nitrogen and carbon co-doped TiO2 particles with a brilliant yellow-orange color were produced mechanochemically by high-energy ball milling as one-pot synthesis. This facile synthesis required only grinding TiO2 with melamine at room temperature. Using monochoromatic lights with the same intensity in visible and UV, the photocatalytic activity of the TiO2 particles was accurately evaluated with respect to the degradation of an aqueous dye (methylene blue) solution. The activities under visible light (450 and 500?nm) were, respectively, 4 and 2 times higher than that of the unmilled TiO2 under UV light (377?nm), corresponding to 9 and 5 times higher than the UV under the solar light condition. The properties and structure of the co-doped TiO2 particles before and after milling were analyzed using eight experimental methods. As a result, it was found that the nitrogen replaced as an oxygen site in milled TiO2 has the highest concertation (2.3%) in the past studies and the structure of milled TiO2 is composed of a polymorphism of four different solid phases of TiO2, gives significant higher photocatalytic activity at visible light than that of UV light. A good repeatability of the photocatalyst was investigated by the number of cycles for the decomposition reaction of the aquesous dye solution.

| S-EPMC6195626 | biostudies-literature

Immobilization of TiO₂ Nanoparticles on Chlorella pyrenoidosa Cells for Enhanced Visible-Light-Driven Photocatalysis.

Project description:TiO₂ nanoparticles are immobilized on chlorella cells using the hydrothermal method. The morphology, structure, and the visible-light-driven photocatalytic activity of the prepared chlorella/TiO₂ composite are investigated by various methods. The chlorella/TiO₂ composite is found to exhibit larger average sizes and higher visible-light intensities. The sensitization of the photosynthesis pigment originating from chlorella cells provides the anatase TiO₂ with higher photocatalytic activities under the visible-light irradiation. The latter is linked to the highly efficient charge separation of the electron/hole pairs. The results also suggest that the photocatalytic activity of the composite remains substantial after four cycles, suggesting a good stability.

| S-EPMC5459020 | biostudies-literature

Sn(IV)porphyrin-Incorporated TiO2 Nanotubes for Visible Light-Active Photocatalysis.

Project description:In this study, two distinct photocatalysts, namely tin(IV)porphyrin-sensitized titanium dioxide nanotubes (SnP-TNTs) and titanium dioxide nanofibers (TNFs), were synthesized and characterized using various spectroscopic techniques. SnP-TNTs were formed through the hydrothermal reaction of NaOH with TiO2 (P-25) nanospheres in the presence of Sn(IV)porphyrin (SnP), resulting in a transformation into Sn(IV)porphyrin-imbedded nanotubes. In contrast, under similar reaction conditions but in the absence of SnP, TiO2 (P-25) nanospheres evolved into nanofibers (TNFs). Comparative analysis revealed that SnP-TNTs exhibited a remarkable enhancement in the visible light photodegradation of model pollutants compared to SnP, TiO2 (P-25), or TNFs. The superior photodegradation activity of SnP-TNTs was primarily attributed to synergistic effects between TiO2 (P-25) and SnP, leading to altered conformational frameworks, increased surface area, enhanced thermo-chemical stability, unique morphology, and outstanding visible light photodegradation of cationic methylene blue dye (MB dye). With a rapid removal rate of 95% within 100 min (rate constant = 0.0277 min-1), SnP-TNTs demonstrated excellent dye degradation capacity, high reusability, and low catalyst loading, positioning them as more efficient than conventional catalysts. This report introduces a novel direction for porphyrin-incorporated catalytic systems, holding significance for future applications in environmental remediation.

| S-EPMC11013583 | biostudies-literature

One-Step Synthesis Heterostructured g-C?N?/TiO? Composite for Rapid Degradation of Pollutants in Utilizing Visible Light.

Project description:To meet the urgent need of society for advanced photocatalytic materials, novel visible light driven heterostructured composite was constructed based on graphitic carbon nitride (g-C?N?) and fibrous TiO?. The g-C?N?/TiO? (CNT) composite was prepared through electrospinning technology and followed calcination process. The state of the g-C?N? and fibrous TiO? was tightly coupled. The photocatalytic performance was measured by degrading the Rhodamine B. Compared to commercial TiO? (P25®) and electrospun TiO? nanofibers, the photocatalytic performance of CNT composite was higher than them. The formation of CNT heterostructures and the enlarged specific surface area enhanced the photocatalytic performance, suppressing the recombination rate of photogenerated carriers while broadening the absorption range of light spectrum. Our studies have demonstrated that heterostructured CNT composite with an appropriate proportion can rational use of visible light and can significantly promote the photogenerated charges transferred at the contact interface between g-C?N? and TiO?.

| S-EPMC6215260 | biostudies-literature

Hydrothermal Synthesis of Fe-Doped Cadmium Oxide Showed Bactericidal Behavior and Highly Efficient Visible Light Photocatalysis.

Project description:Cationic dyes present in industrial effluents significantly reduce the effectiveness of remediation operations. Considering the terrible impact of these pollutants on environment and biodiversity, investigating strategies to remove potentially harmful compounds from water is becoming an increasingly intriguing issue. In this work, we employed a simple hydrothermal technique to synthesize Fe-doped CdO (2, 4, and 6 wt %) nanostructures and assessed their efficacy in degrading methylene blue (MB) dye and inhibiting the growth of Staphylococcus aureus and Escherichia coli, respectively. Structural, morphological, and optical characterization of produced nanomaterials was also performed using X-ray diffraction, TEM, and UV absorption spectra. The photocatalytic decomposition of MB was significantly enhanced (58.8%) by using Fe (6 wt %)-doped CdO catalysts for 80 min under irradiation. In addition, 2.05-5.05 mm inhibitory zones were seen against Gram-positive bacteria (S. aureus), whereas the range for Gram-negative bacteria (E. coli) was 1.65-2.75 mm. These nanostructures were shown to be very effective inhibitors of beta-lactamase, d-alanine-d-alanine ligase B, and fatty acid synthase inhibitor by in silico molecular docking investigations.

| S-EPMC10448685 | biostudies-literature

Heterostructured TiO2/SiO2/γ-Fe2O3/rGO Coating with Highly Efficient Visible-Light-Induced Self-Cleaning Properties for Metallic Artifacts.

Project description:A novel nanohybrid composite of TiO2, SiO2, γ-Fe2O3, and reduced graphene oxide (TiO2@Si:Fe:rGO) is fabricated by the sol-gel method. The properties of the coated film were examined by structural and self-cleaning analyses using simulated discoloration/soiling and roofing tests. The fabricated transparent TiO2@Si:Fe:rGO composite showed excellent photoactivity and wettability, behaving well in self-cleaning applications. The addition of SiO2 improved the crystalline structure and surface hydroxylation of TiO2 nanoparticles. γ-Fe2O3 decreased the recombination rate of e-/h+ pairs, and significantly improved photocatalytic activity under visible light. Moreover, rGO sheets as excellent electron acceptors and transporters also reduced recombination, as well as affected wettability, achieving superhydrophilicity under irradiation. The coated substrate showed excellent resistance to simulated acid rain and significantly preserved the substrate from soiling in roofing tests.

| S-EPMC8153401 | biostudies-literature

Titanium dioxide visible light photocatalysis: surface association enables photocatalysis with visible light irradiation.

Project description:Titanium dioxide (TiO2) is a widely employed and inexpensive photocatalyst, but its use in organic synthesis has been limited by the short-wavelength ultraviolet irradiation typically used. We have discovered that TiO2 particles efficiently mediate photocatalytic radical cation Diels-Alder cycloadditions using a simple visible light source, enabled by the formation of a visible light absorbing complex of the substrate on the semiconductor surface.

| S-EPMC5657382 | biostudies-literature

Noble Metal-Free TiO2-Coated Carbon Nitride Layers for Enhanced Visible Light-Driven Photocatalysis.

Project description:Composites of g-C3N4/TiO2 were one-step prepared using electron impact with dielectric barrier discharge (DBD) plasma as the electron source. Due to the low operation temperature, TiO2 by the plasma method shows higher specific surface area and smaller particle size than that prepared via conventional calcination. Most interestingly, electron impact produces more oxygen vacancy on TiO2, which facilitates the recombination and formation of heterostructure of g-C3N4/TiO2. The composites have higher light absorption capacity and lower charge recombination efficiency. g-C3N4/TiO2 by plasma can produce hydrogen at a rate of 219.9 ?mol·g-1·h-1 and completely degrade Rhodamine B (20mg·L-1) in two hours. Its hydrogen production rates were 3 and 1.5 times higher than that by calcination and pure g-C3N4, respectively. Electron impact, ozone and oxygen radical also play key roles in plasma preparation. Plasma has unique advantages in metal oxides defect engineering and the preparation of heterostructured composites with prospective applications as photocatalysts for pollutant degradation and water splitting.

| S-EPMC7221541 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data