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Effective La-Na Co-Doped TiO? Nano-Particles for Dye Adsorption: Synthesis, Characterization and Study on Adsorption Kinetics.

ABSTRACT: The mesoporous La-Na co-doped TiO? nanoparticles (NPs) have been synthesized by non-aqueous, solvent-controlled, sol-gel route. The substitutional doping of large sized Na+1 and La+3 at Ti4+ is confirmed by X-ray diffraction (XRD) and further supported by Transmission Electron Microscopy (TEM) and X-ray Photo-electron Spectroscopy (XPS). The consequent increase in adsorbed hydroxyl groups at surface of La-Na co-doped TiO? results in decrease in pHIEP, which makes nanoparticle surface more prone to cationic methylene blue (MB) dye adsorption. The MB dye removal was examined by different metal doping, pH, contact time, NPs dose, initial dye concentration and temperature. Maximum dye removal percentage was achieved at pH 7.0. The kinetic analysis suggests adsorption dynamics is best described by pseudo second-order kinetic model. Langmuir adsorption isotherm studies revealed endothermic monolayer adsorption of Methylene Blue dye.

SUBMITTER: Singh I

PROVIDER: S-EPMC6474146 | biostudies-literature | 2019 Mar

REPOSITORIES: biostudies-literature

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Effective La-Na Co-Doped TiO₂ Nano-Particles for Dye Adsorption: Synthesis, Characterization and Study on Adsorption Kinetics.

Singh Inderjeet I Birajdar Balaji B

Nanomaterials (Basel, Switzerland) 20190309 3

The mesoporous La-Na co-doped TiO₂ nanoparticles (NPs) have been synthesized by non-aqueous, solvent-controlled, sol-gel route. The substitutional doping of large sized Na+1 and La+3 at Ti4+ is confirmed by X-ray diffraction (XRD) and further supported by Transmission Electron Microscopy (TEM) and X-ray Photo-electron Spectroscopy (XPS). The consequent increase in adsorbed hydroxyl groups at surface of La-Na co-doped TiO₂ results in decrease in pHIEP, ...[more]

PMID: 30857307

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Project description:The adsorption behavior of an organic dye, metanil yellow (My), from water using micro-nano silica particles (MNSPs) was investigated. MCM-41-like (Mobil Composition of Matter No. 41) MNSPs were synthesized using tetraethoxy orthosilicate as a silica source and hexadecyltrimethylammonium bromide (CTAB) as a surfactant under basic conditions. Comparative studies were performed to assess the adsorption behaviors of the organic dye using the as-synthesized MCM-41 before the removal of CTAB and MCM-41, either after one, two, and three times of chemical etching or after calcination. My was adsorbed more effectively from water on the as-synthesized MCM-41 without the removal of the surfactant than on MCM-41 after the removal of the surfactant by chemical etching or calcination. In addition, MCM-41 after removing the surfactant by one-time chemical etching in the presence of hydrochloric acid also showed better adsorption of My from water than MCM-41 after removing the surfactant by further two and three times of chemical etching or calcination. For comparison, other kinds of dye molecules with different chemical structures such as methylene blue (Mb) and rhodamine B (Rb) were also used to check the possibility of adsorption of various dyes by the CTAB-supported MNSPs. To better understand the reason behind the adsorption phenomena, detailed studies on the kinetics and thermodynamics of adsorption of the MNSPs were performed. Excellent adsorption of My was observed at concentrations up to 100 mg L-1 at 25 °C, whereas the adsorption was lower at higher concentrations of the My dye. Furthermore, enhanced My dye adsorption was observed at higher concentrations by increasing the adsorption temperature. It can be concluded that the MNSPs exhibited efficient adsorption of My, when the MNSPs are used without the removal of the surfactant and any further modifications, suggesting that the surfactant played key roles in the effective adsorption of the anionic dye. The as-synthesized MCM-41 was, however, not a good adsorbent for cationic dyes such as Mb and Rb.

Project description:Copper-doped TiO2 was prepared with a sol-gel chemical method. Various concentrations (3, 6, and 9 wt%) of Cu dopant were employed. Several techniques were implemented to assess the structural, optical, morphological and chemical properties of the synthesized samples. Evaluation of elemental composition using SEM-EDS and XRF techniques showed the presence of dopant element in the prepared samples. XRD analysis confirmed the presence of anatase (TiO2) phase with interstitial doping. Incorporation of dopant was observed to enhance the crystallinity and increase the crystallite size of the synthesized products. SAED profiles revealed a high degree of crystallinity in the prepared specimens, which was also evident in the XRD spectra. Optical properties studied using UV-vis spectroscopy depicted a shift of the maximum absorption to the visible region (redshift) that signified a reduction in the band gap energy of Cu-doped TiO2 samples. Examination of morphological features with scanning and high-resolution transmission electron microscopes revealed the formation of spherical nanoparticles with a tendency to agglomerate with increasing dopant concentration. Molecular vibrations and the formation of Ti-O-Ti bonds were revealed through FTIR spectra. PL spectroscopy recorded the trapping efficiency and migration of charge carriers, which exhibited electron-hole recombination behavior. Doped nanostructures showed enhanced bactericidal performance and synergism against S. aureus and E. coli. In summary, Cu-doped TiO2 nanostructures were observed to impede bacteria effectively, which is deemed beneficial in overcoming ailments caused by pathogens such as microbial etiologies. Furthermore, molecular docking analysis was conducted to study the interaction of Cu-doped TiO2 nanoparticles with multiple proteins namely β-lactamase (binding score: -4.91 kcal mol-1), ddlB (binding score: -5.67 kcal mol-1) and FabI (binding score: -6.13 kcal mol-1) as possible targets with active site residues. Dye degradation/reduction of control and Cu-doped samples were studied through absorption spectroscopy. The obtained outcomes of the performed experiment indicated that the photocatalytic activity of Cu-TiO2 enhanced with increasing dopant concentration, which is thought to be due to a decreased rate of electron-hole pair recombination. Consequently, it is suggested that Cu-TiO2 can be exploited as an effective candidate for antibacterial and dye degradation applications.

Dataset Information

Effective La-Na Co-Doped TiO? Nano-Particles for Dye Adsorption: Synthesis, Characterization and Study on Adsorption Kinetics.

Publications

Effective La-Na Co-Doped TiO₂ Nano-Particles for Dye Adsorption: Synthesis, Characterization and Study on Adsorption Kinetics.

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