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Highly Selective, Efficient Deoxygenative Hydrogenation of Amides Catalyzed by a Manganese Pincer Complex via Metal-Ligand Cooperation.

ABSTRACT: Deoxygenative hydrogenation of amides to amines homogeneously catalyzed by a complex of an Earth-abundant metal is presented. This manganese-catalyzed reaction features high efficiency and selectivity. A plausible reaction mechanism, involving metal-ligand cooperation of the manganese pincer complex, is proposed based on NMR studies and relevant stoichiometric reactions.

SUBMITTER: Zou YQ 

PROVIDER: S-EPMC6503579 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature

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Highly Selective, Efficient Deoxygenative Hydrogenation of Amides Catalyzed by a Manganese Pincer Complex via Metal-Ligand Cooperation.

Zou You-Quan YQ   Chakraborty Subrata S   Nerush Alexander A   Oren Dror D   Diskin-Posner Yael Y   Ben-David Yehoshoa Y   Milstein David D  

ACS catalysis 20180730 9

Deoxygenative hydrogenation of amides to amines homogeneously catalyzed by a complex of an Earth-abundant metal is presented. This manganese-catalyzed reaction features high efficiency and selectivity. A plausible reaction mechanism, involving metal-ligand cooperation of the manganese pincer complex, is proposed based on NMR studies and relevant stoichiometric reactions. ...[more]

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