Dataset Information

Biomass-Templated Fabrication of Metallic Materials for Photocatalytic and Bactericidal Applications.

ABSTRACT: In this paper, we report a simple, feasible and low-cost method to fabricate self-standing metallic materials using cellulose-based biomass as sacrificial templates. This process involves the impregnation of metallic precursors to the cellulose fibers of biomass templates and the transformation of the precursors to corresponding metals or metal oxides (as well as the removal of the cellulose framework) at an elevated temperature. The structures of the metallic materials as fabricated take the form of architectures of biomass templates (e.g., chromatography paper, medical absorbent cotton, catkins of reed, seed balls of oriental plane, and petals of peach blossom), and the various kinds of metals and metal oxides fabricated with these templates include silver, gold, anatase, cupric oxide, zinc oxide, etc. We have demonstrated photocatalytic and bactericidal applications of such metallic materials, and they should find more applications in electronics, catalysis, energy storage, biomedicine and so on.

SUBMITTER: Guo X

PROVIDER: S-EPMC6514999 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Similar Datasets

Project description:In this article, ZnO:NiO:CuO nanocomposites (NCPs) were synthesized using a hydrothermal method, with different Zn : Ni : Cu molar ratios (1 : 1 : 1, 2 : 1 : 1, 1 : 2 : 1, and 1 : 1 : 1). The PXRD confirmed the formation of a NCP consisting of ZnO (hexagonal), NiO (cubic), and CuO (monoclinic) structures. The crystallite sizes of NCPs were calculated using Debye Scherrer and Williamson-Hall methods. The calculated crystalline sizes (Scherrer method) of the NCPs were determined to be 21, 27, 23, and 20 nm for the molar ratios 1 : 1 : 1, 2 : 1 : 1, 1 : 2 : 1, and 1 : 1 : 2, respectively. FTIR spectra confirmed the successful formation of heterojunction NCPs via the presence of metal-oxygen bonds. The UV-vis spectroscopy was used to calculate the bandgap of synthesized samples and was found in the range of 2.99-2.17 eV. SEM images showed the mixed morphology of NCPs i.e., irregular spherical and rod-like structures. The dielectric properties, including AC conductivity, dielectric constant, impedance, and dielectric loss parameters were measured using an LCR meter. The DC electrical measurements revealed that NCPs have a high electrical conductivity. All the NCPs were evaluated for the photocatalytic degradation of Methylene blue (MB), methyl orange (MO), and a mixture of both of these dyes. The NCPs with a molar ratio 1 : 1 : 2 (Zn : Ni : Cu) displayed outstanding photocatalytic activity under sunlight, achieving the degradation efficiency of 98% for methylene blue (MB), 92% for methyl orange (MO) and more than 87% in the case of a mixture of dyes within just 90 minutes of illumination. The antibacterial activity results showed the more noxious nature of NCPs against Gram-negative bacteria with a maximum zone of inhibition revealed by the NCPs of molar ratio 1 : 2 : 1 (Zn : Ni : Cu). On the basis of these observations, it can be anticipated that the NCPs can be successfully employed for the purification of contaminated water by the degradation of hazardous organic compounds and in antibacterial ointments.

Dataset Information

Biomass-Templated Fabrication of Metallic Materials for Photocatalytic and Bactericidal Applications.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets