Ontology highlight
ABSTRACT:
SUBMITTER: Anneser MR
PROVIDER: S-EPMC6546507 | biostudies-literature | 2019 Jun
REPOSITORIES: biostudies-literature
Anneser Markus R MR Elpitiya Gaya R GR Townsend Jacob J Johnson Elizabeth J EJ Powers Xian B XB DeJesus Joseph F JF Vogiatzis Konstantinos D KD Jenkins David M DM
Angewandte Chemie (International ed. in English) 20190507 24
Three five-coordinate iron(IV) imide complexes have been synthesized and characterized. These novel structures have disparate spin states on the iron as a function of the R-group attached to the imide, with alkyl groups leading to low-spin diamagnetic (S=0) complexes and an aryl group leading to an intermediate-spin (S=1) complex. The different spin states lead to significant differences in the bonding about the iron center as well as the spectroscopic properties of these complexes. Mössbauer sp ...[more]