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ABSTRACT:
SUBMITTER: Iluc VM
PROVIDER: S-EPMC3192028 | biostudies-literature | 2011 Aug
REPOSITORIES: biostudies-literature
Iluc Vlad M VM Iluc Vlad M VM Miller Alexander J M AJ Anderson John S JS Monreal Marisa J MJ Mehn Mark P MP Hillhouse Gregory L GL
Journal of the American Chemical Society 20110728 33
A new family of low-coordinate nickel imides supported by 1,2-bis(di-tert-butylphosphino)ethane was synthesized. Oxidation of nickel(II) complexes led to the formation of both aryl- and alkyl-substituted nickel(III)-imides, and examples of both types have been isolated and fully characterized. The aryl substituent that proved most useful in stabilizing the Ni(III)-imide moiety was the bulky 2,6-dimesitylphenyl. The two Ni(III)-imide compounds showed different variable-temperature magnetic proper ...[more]