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Silanediol Anion Binding and Enantioselective Catalysis.

ABSTRACT: Silanediols possess unique and complementary catalytic activity in reactions that are likely to proceed through anion binding. This article directly compares silanediols, thioureas, and squaramides in three separate anion-binding processes. The catalytic abilities of select members of each family are directly correlated to association constant.

SUBMITTER: Attard JW

PROVIDER: S-EPMC6548508 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature

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Silanediol Anion Binding and Enantioselective Catalysis.

Attard Jonathan W JW Osawa Kohei K Guan Yong Y Hatt Jessica J Kondo Shin-Ichi SI Mattson Anita A

Synthesis 20190312 10

Silanediols possess unique and complementary catalytic activity in reactions that are likely to proceed through anion binding. This article directly compares silanediols, thioureas, and squaramides in three separate anion-binding processes. The catalytic abilities of select members of each family are directly correlated to association constant. ...[more]

PMID: 31178610

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