Ontology highlight
ABSTRACT:
SUBMITTER: Shi H
PROVIDER: S-EPMC6549977 | biostudies-literature | 2019 May
REPOSITORIES: biostudies-literature
Royal Society open science 20190501 5
The mechanism was proposed of heterogeneous catalytic CO<sub>2</sub> absorptions with primary/secondary amines involving 'catalytic carbamate formation'. Compared with the non-catalytic 'Zwitterion mechanism', this Eley-Rideal model was proposed for CO<sub>2</sub> + RR'NH with MCO<sub>3</sub> (M = Ca, Mg, and Ba) with four elementary reaction steps: (B1) amine adsorption, (B2) Zwitterion formation, (B3) carbamate formation, and (B4) carbamate desorption. The rate law if determining step of each ...[more]