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Room-Temperature Fabrication of a Nickel-Functionalized Copper Metal?Organic Framework (Ni@Cu-MOF) as a New Pseudocapacitive Material for Asymmetric Supercapacitors.

ABSTRACT: A nickel-functionalized copper metal-organic framework (Ni@Cu-MOF) was prepared by a facile volatilization method and a post-modification synthesis method at room temperature. The obtained Ni@Cu-MOF electrode delivered a high capacitance of 526 F/g at 1 A/g and had a long-term cycling stability (80% retention after 1200 cycles at 1 A/g) in a 6 M KOH aqueous solution. Furthermore, an asymmetric supercapacitor device was assembled from this Ni@Cu-MOF and activated carbon electrodes. The fabricated supercapacitor delivered a high capacitance of 48.7 F/g at 1 A/g and a high energy density of 17.3 Wh/kg at a power density of 798.5 kW/kg. This study indicates that the Ni@Cu-MOF has great potential for supercapacitor applications.

SUBMITTER: Wang Y

PROVIDER: S-EPMC6572177 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature

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Room-Temperature Fabrication of a Nickel-Functionalized Copper Metal⁻Organic Framework (Ni@Cu-MOF) as a New Pseudocapacitive Material for Asymmetric Supercapacitors.

Wang Yi Y Nie Shengqiang S Liu Yuan Y Yan Wei W Lin Shaomin S Cheng Gang G Yang Huan H Luo Jun J

Polymers 20190507 5

A nickel-functionalized copper metal-organic framework (Ni@Cu-MOF) was prepared by a facile volatilization method and a post-modification synthesis method at room temperature. The obtained Ni@Cu-MOF electrode delivered a high capacitance of 526 F/g at 1 A/g and had a long-term cycling stability (80% retention after 1200 cycles at 1 A/g) in a 6 M KOH aqueous solution. Furthermore, an asymmetric supercapacitor device was assembled from this Ni@Cu-MOF and activated carbon electrodes. The fabricated ...[more]

PMID: 31067738

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