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A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol.

ABSTRACT: For the first time, structurally defined manganese pincer complexes catalyze the dehydrogenation of aqueous methanol to hydrogen and carbon dioxide, which is a transformation of interest with regard to the implementation of a hydrogen and methanol economy. Excellent long-term stability was demonstrated for the Mn-PNPiPr catalyst, as a turnover of more than 20?000 was reached. In addition to methanol, other important hydrogen carriers were also successfully dehydrogenated.

SUBMITTER: Anderez-Fernandez M

PROVIDER: S-EPMC6586016 | biostudies-literature | 2017 Jan

REPOSITORIES: biostudies-literature

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A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol.

Andérez-Fernández María M Vogt Lydia K LK Fischer Steffen S Zhou Wei W Jiao Haijun H Garbe Marcel M Elangovan Saravanakumar S Junge Kathrin K Junge Henrik H Ludwig Ralf R Beller Matthias M

Angewandte Chemie (International ed. in English) 20161202 2

For the first time, structurally defined manganese pincer complexes catalyze the dehydrogenation of aqueous methanol to hydrogen and carbon dioxide, which is a transformation of interest with regard to the implementation of a hydrogen and methanol economy. Excellent long-term stability was demonstrated for the Mn-PNPiPr catalyst, as a turnover of more than 20 000 was reached. In addition to methanol, other important hydrogen carriers were also successfully dehydrogenated. ...[more]

PMID: 27910197

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