Ontology highlight
ABSTRACT:
SUBMITTER: Ellis WC
PROVIDER: S-EPMC6596426 | biostudies-literature | 2018
REPOSITORIES: biostudies-literature
Ellis W Chadwick WC Ryabov Alexander D AD Fischer Andreas A Hayden Joshua A JA Shen Longzhu Q LQ Bominaar Emile L EL Hendrich Michael P MP Collins Terrence J TJ
Journal of coordination chemistry 20180629 11-13
The preparation, characterization, and evaluation of a cobalt(III) complex with 13-membered tetraamide macrocyclic ligand (TAML) is described. This is a square-planar (X-ray) <i>S</i> = 1 paramagnetic (<sup>1</sup>H NMR) compound, which becomes an <i>S</i> = 0 diamagnetic octahedral species in excess d<sub>5</sub>-pyridine. Its one-electron oxidation at an electrode is fully reversible with the lowest <i>E</i> <sub>1/2</sub> value (0.66 V <i>vs</i> SCE) among all investigated Co<sup>III</sup> TA ...[more]