Electrochemical Reduction of CO₂ to Formate on Easily Prepared Carbon-Supported Bi Nanoparticles.

ABSTRACT: Herein, the electrochemical reduction of CO₂ to formate on carbon-supported bismuth nanoparticles is reported. Carbon-supported Bi nanoparticles (about 10 nm in size) were synthesized using a simple, fast and scalable approach performed under room conditions. The so-prepared Bi electrocatalyst was characterized by different physicochemical techniques, including transmission electron microscopy, X-ray photoelectron spectroscopy, and X-ray diffraction and subsequently air-brushed on a carbon paper to prepare electrodes. These electrodes were characterized by scanning electron microscopy, energy-dispersive X-ray spectroscopy and also by cyclic voltammetry. Finally, CO₂ electroreduction electrolyses were performed at different electrode potentials for 3 h. At the optimal electrode potential (-1.6 V vs AgCl/Ag), the concentration of formate was about 77 mM with a faradaic efficiency of 93 ± 2.5%. A 100% faradaic efficiency was found at a lower potential (-1.5 V vs AgCl/Ag) with a formate concentration of about 55 mM. In terms of stability, we observed that after about 70 h (in 3 h electrolysis experiments at different potentials), the electrode deactivates due to the gradual loss of metal as shown by SEM/EDX analyses of the deactivated electrodes.

SUBMITTER: Avila-Bolivar B 

PROVIDER: S-EPMC6600365 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature