Ontology highlight
ABSTRACT:
SUBMITTER: McConnell CR
PROVIDER: S-EPMC6609151 | biostudies-literature | 2019 Jun
REPOSITORIES: biostudies-literature
McConnell Cameron R CR Haeffner Fredrik F Baggett Andrew W AW Liu Shih-Yuan SY
Journal of the American Chemical Society 20190523 22
Two new 1,2-azaborine building blocks that enable the broad diversification of previously not readily accessible C4 and C5 ring positions of the 1,2-azaborine heterocycle are developed. 1,2-Azaborine's distinct electronic structure allowed the resolution of a mixture of C4- and C5-borylated 1,2-azaborines. The connection between the electronic structure of C4 and C5 positions of 1,2-azaborine and their distinct reactivity patterns is revealed by a combination of reactivity studies and kinetic me ...[more]