Ontology highlight
ABSTRACT:
SUBMITTER: Schieweck BG
PROVIDER: S-EPMC6611062 | biostudies-literature | 2019 Jul
REPOSITORIES: biostudies-literature
Schieweck Benjamin G BG Westhues Niklas F NF Klankermayer Jürgen J
Chemical science 20190531 26
Herein a highly active non-precious transition metal catalyst system for homogeneous hydrogenation of carbon dioxide to formate is presented. The application of selected nickel(ii) salts in combination with tailored multidentate ligands enabled the effective transformation of carbon dioxide with an exceptional TON of up to 4.65 × 10<sup>6</sup>. This unprecedented productivity based on the novel nickel catalyst not only outmatches that of existing systems containing first row transition metals, ...[more]